Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

Z Ni, H Lv, G Yang - Molecules, 2022 - mdpi.com
Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have
received considerable research attention due to their structural versatility and diverse …

A Zr-added Dawson-type poly (polyoxometalate)

HL Li, C Lian, GY Yang - Dalton Transactions, 2023 - pubs.rsc.org
A novel Zr-added trimer,[H2N (CH3) 2] 10H14 [(Zr2P2W16O61) 3]· 7H2O (1), has been
made under hydrothermal conditions, and contains the highest number of Zr centers in …

Two unusual nanosized Nd 3+-substituted selenotungstate aggregates simultaneously comprising lacunary Keggin and Dawson polyoxotungstate segments

H Li, C Lian, L Chen, J Zhao, GY Yang - Nanoscale, 2020 - pubs.rsc.org
Two unique nanosized Nd3+-substituted selenotungstates Na9K8 {[W3Nd2 (H2O) 3 (NO3)
O6](B-α-SeW9O33) 2 (α-Se2W14O52)}· 35H2O (1) and [H2N (CH3) 2] 7H9Na4 {[W2Nd2 …

Four octamolybdate complexes constructed from a quinoline–imidazole–monoamide ligand: structures and electrochemical, photocatalytic and magnetic properties

L Li, X Wang, N Xu, Z Chang, G Liu, H Lin, X Wang - CrystEngComm, 2020 - pubs.rsc.org
By introducing a quinoline–imidazole–monoamide ligand, N-(quinoline-5-yl)-1H-imidazole-
4-carboxamide (L), into reaction systems containing a [Mo7O24] 6− polyoxoanion and …

Organic–inorganic hybrid cerium-encapsulated selenotungstate including three building blocks and its electrochemical detection of dopamine and paracetamol

J Jiang, L Liu, G Liu, D Wang, Y Zhang… - Inorganic …, 2020 - ACS Publications
A novel organic–inorganic hybrid cerium-encapsulated selenotungstate comprising three
polyoxotungstate building units Na16H6 {[Ce3W4O10 (H2O) 9 (CH3COO) 3] 2 …

First series of mixed (P III, Se IV)-heteroatomoriented rare-earth-embedded polyoxotungstates containing distinct building blocks

L Liu, J Jiang, X Liu, G Liu, D Wang, L Chen… - Inorganic Chemistry …, 2020 - pubs.rsc.org
By a self-assembly reaction strategy accompanying the step-by-step introduction of simple
reactants, a series of unprecedented mixed-heteroatom-oriented rare-earth-embedded …

Self-assembly of nanoscale lanthanoid-containing selenotungstates: synthesis, structures, and magnetic studies

WC Chen, CQ Jiao, XL Wang, KZ Shao… - Inorganic …, 2019 - ACS Publications
The reaction of mid-lanthanide (Ln) ions with the preformed {Se6W39} precursor under
reasonably acidic aqueous conditions in the presence of organic amine cations results in an …

Assembly of tetra-nuclear Yb III-containing selenotungstate clusters: Synthesis, structures, and magnetic properties

LZ Han, CQ Jiao, WC Chen, KZ Shao, LY Jin… - Dalton …, 2021 - pubs.rsc.org
Two tetra-nuclear YbIII-incorporated selenotungstate clusters, Keggin (C2H8N) 6Na14
[Yb4Se6W44O160 (H2O) 12]· 40H2O (1) and Wells–Dawson (C2H8N) 4Na14 …

Rare-earth and antimony-oxo clusters simultaneously connecting antimonotungstates comprising divacant and tetravacant Keggin fragments

X Xu, Y Chen, Y Zhang, Y Liu, L Chen… - Inorganic Chemistry, 2019 - ACS Publications
Four novel rare-earth (RE) and Sb-oxo clusters simultaneously bridging antimonotungstates
(ATs)[H2N (CH3) 2] 8Na6H8 {[RE4 (H2O) 6Sb6O4](SbW10O37) 2 (SbW8O31) 2}· 24H2O …

Multi-nuclear rare-earth-implanted tartaric acid-functionalized selenotungstates and their fluorescent and magnetic Properties

J Liu, D Wang, X Xu, H Li, J Zhao, L Chen - Inorganic Chemistry, 2021 - ACS Publications
A family of multinuclear rare-earth (RE)-implanted H2tart2–-functionalized selenotungstates
(STs)[H2N (CH3) 2] 13H {[W2O5 (OH) 2 (H2tart) 2](H2tart){[W3O6RE2 (H2O) 6][SeW9O33] …