Chalcogenide glass-ceramics: Functional design and crystallization mechanism

C Lin, C Rüssel, S Dai - Progress in Materials Science, 2018 - Elsevier
Chalcogenide glasses are defined as a new category of non-crystalline solids on the basis
of their characteristic covalent bonds and unique properties, such as broad infrared …

Relaxation and physical aging in network glasses: a review

M Micoulaut - Reports on Progress in Physics, 2016 - iopscience.iop.org
Recent progress in the description of glassy relaxation and aging are reviewed for the wide
class of network-forming materials such as GeO 2, Ge x Se 1− x, silicates (SiO 2–Na 2 O) or …

Boson peak, heterogeneity and intermediate-range order in binary SiO2-Al2O3 glasses

MF Ando, O Benzine, Z Pan, JL Garden… - Scientific reports, 2018 - nature.com
In binary aluminosilicate liquids and glasses, heterogeneity on intermediate length scale is a
crucial factor for optical fiber performance, determining the lower limit of optical attenuation …

Structure, topology, rings, and vibrational and electronic properties of GeSe glasses across the rigidity transition: A numerical study

M Micoulaut, A Kachmar, M Bauchy, S Le Roux… - Physical Review B …, 2013 - APS
The structural, electronic, and vibrational properties of glassy Ge x Se 1− x are studied using
density-functional-based molecular dynamics. The focus is on four compositions (x= 10 …

Densified network glasses and liquids with thermodynamically reversible and structurally adaptive behaviour

M Bauchy, M Micoulaut - Nature Communications, 2015 - nature.com
If crystallization can be avoided during cooling, a liquid will display a substantial increase of
its viscosity, and will form a glass that behaves as a solid with a relaxation time that grows …

Viscosity, Boson Peak and Elastic Moduli in the Na2O-SiO2 System

M Cassetta, G Mariotto, N Daldosso, E De Bona… - Minerals, 2023 - mdpi.com
The temperature and chemical dependence of the melt viscosity are ubiquitous in the model
development of the volcanic dynamics, as well as in the glass production and design. We …

Method for determining resin cure kinetics with low-frequency Raman spectroscopy

RV Chimenti, AM Lehman-Chong, AM Sepcic… - Analyst, 2023 - pubs.rsc.org
Characterizing resin extent of cure kinetics is critical to understanding the structure–property-
processing relationships of polymers. The disorder band present in the low-frequency region …

Melt Homogenization and Self‐Organization in Chalcogenides‐Part II

S Bhosle, K Gunasekera, P Boolchand… - … Journal of Applied …, 2012 - Wiley Online Library
The compositional variation of the non‐reversing enthalpy at Tg, ΔHnr (x), in GexSe100− x
glasses decreases abruptly by an order of magnitude as x increases to xc (1)= 19.5 (5) …

Structure-terahertz property relationship and femtosecond laser irradiation effects in chalcogenide glasses

NJ Tostanoski, EJ Heilweil, PF Wachtel… - Journal of Non …, 2023 - Elsevier
We report structure-terahertz (THz) property relationship for various non-oxide chalcogenide
glasses including unary (vitreous selenium (Se)), binary (arsenic sulfide (As-S), arsenic …

Network Structure in GeS2–Sb2S3 Chalcogenide Glasses: Raman Spectroscopy and Phase Transformation Study

C Lin, Z Li, L Ying, Y Xu, P Zhang, S Dai… - The Journal of …, 2012 - ACS Publications
Structural order beyond the next-nearest-neighbor structural units is of great interest in
network glasses, especially in chalcogenide glasses, but little specific description can be …