Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Removal and utilization of capping agents in nanocatalysis

Z Niu, Y Li - Chemistry of Materials, 2014 - ACS Publications
Capping agents are frequently used in colloidal synthesis to inhibit nanoparticle overgrowth
and aggregation as well as to control the structural characteristics of the resulted …

The role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts

LM Rossi, JL Fiorio, MAS Garcia, CP Ferraz - Dalton Transactions, 2018 - pubs.rsc.org
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …

[HTML][HTML] Addressing complexity in catalyst design: From volcanos and scaling to more sophisticated design strategies

SM Stratton, S Zhang, MM Montemore - Surface Science Reports, 2023 - Elsevier
Volcano plots and scaling relations are commonly used to design catalysts and understand
catalytic behavior. These plots are a useful tool due to their robust and simple analysis of …

Controlling the surface environment of heterogeneous catalysts using self-assembled monolayers

CA Schoenbaum, DK Schwartz… - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Rationally designing and producing suitable catalysts to promote specific
reaction pathways remains a major objective in heterogeneous catalysis. One approach …

Integrating Electrochemical CO2 Reduction on α-NiS with the Water or Organic Oxidations by Its Electro-Oxidized NiO(OH) Counterpart to an Artificial Photosynthetic …

A Kundu, B Kumar, A Rajput… - ACS Applied Materials & …, 2023 - ACS Publications
Efficient hydrogen production, biomass up-conversion, and CO2-to-fuel generation are the
key challenges of the present decade. Electrocatalysis in aqueous electrolytes by choosing …

Rational design of noble metal-based multimetallic nanomaterials: A review

BA Yusuf, W Yaseen, J Xie, AA Babangida… - Nano Energy, 2022 - Elsevier
The functionalized and synergistic properties of noble metal-based multimetallic
nanomaterials (NMMMs) have gained a significant amount of consideration for their diverse …

Colloidal nanocrystals as building blocks for well-defined heterogeneous catalysts

M Cargnello - Chemistry of Materials, 2019 - ACS Publications
The goal of this perspective is to highlight the use of colloidal nanocrystals in the preparation
of heterogeneous catalysts of well-defined structures with the objective to advance catalytic …

Catalytic Hydrodehydroxylation of Biomass-Related Chemicals via Water-Mediated Hydrogen Heterolysis over a Pd–S Interface

Q Deng, J Lu, G Sheng, YC Zhang, J Wang… - ACS …, 2023 - ACS Publications
Traditionally partial sulfur-poisoned Pd is used to enhance selectivity in hydrogenation
reactions. Herein, we report that this type of catalyst can also display ultraselective …