1.1. General Considerations Palladium catalysis is one of the most important synthetic tools
in modern organic synthesis. A particularly attractive synthetic feature of palladium catalysis …

Ligands in coordination chemistry and homogeneous catalysis are traditionally “static”
spectators that do not actively participate in the catalytic cycle. However, such classic …

Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …

Organoselenium ligands are building blocks of several transition metal complexes which
catalyze various organic reactions efficiently in solution. In this review the survey of …

The selective functionalization of alkanes and alkyl groups is a major goal of chemical
catalysis. Toward this end, a bulky triphosphine with a central secondary phosphino group …

Transition-metal pincer complexes have been the subject of numerous reactivity studies that
range from explorations of catalytic activity to investigations of challenging bond-activation …

The coordination chemistry of an N-heterocyclic phosphenium (NHP)-containing bis
(phosphine) pincer ligand has been explored with Pt0 and Pd0 precursors. Unlike previous …

Heck cross coupling reactions have been catalyzed with several palladium (II)-complexes of
organochalcogen ligands. The complexes applied in molecular and tethered forms appear …

The synthesis and characterization of a new series of Pt (II) complexes bearing the tridentate
bis (phosphino) silyl ligands [κ3-(2-R2 P C6H4) 2 Si Me]−([R-PSiP], R= Ph, Cy) are reported …

In der Koordinationschemie sowie in der homogenen Katalyse werden Liganden
üblicherweise als “statische” Molekülteile betrachtet, die nicht aktiv in den Katalysezyklus …