Recent advances in sustainable N-heterocyclic carbene-Pd (II)-pyridine (PEPPSI) catalysts: A review

GRP Vasu, KRM Venkata, RR Kakarla… - Environmental …, 2023 - Elsevier
Various catalysts in homogeneous or heterogeneous catalysis deploy unconventional
reaction pathways by lowering the activation energy (AE) barrier, controlling the selectivity …

Coordination versatility of NHC-metal topologies in asymmetric catalysis: Synthetic insights and recent trends

A Jayaraj, AV Raveedran, AT Latha… - Coordination Chemistry …, 2023 - Elsevier
Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …

Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route

T Scattolin, AA Logvinov, NV Tzouras, CSJ Cazin… - …, 2023 - ACS Publications
N-heterocyclic carbene (NHC) ligands have evolved from being simple lab curiosities to
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …

Classes of amides that undergo selective N–C amide bond activation: The emergence of ground-state destabilization

P Gao, MM Rahman, A Zamalloa… - The Journal of …, 2022 - ACS Publications
Ground-state destabilization of the N–C (O) linkage represents a powerful tool to
functionalize the historically inert amide bond. This burgeoning reaction manifold relies on …

Nickel-Catalyzed Electro-Reductive Cross-Coupling of Aliphatic N-Acyl Imides with Alkyl Halides as a Strategy for Dialkyl Ketone Synthesis: Scope and Mechanistic …

T Kerackian, D Bouyssi, G Pilet, M Médebielle… - ACS …, 2022 - ACS Publications
The development and in-depth study of a cross-electrophile coupling of alkyl N-acyl imides
with alkyl halides relying on the combination of nickel catalysis and electrochemistry are …

Recent advances in the synthesis of benzo [b] thiophene fused polycyclic derivatives: Strategies and reactions

J Huang, W Wang, L Zhang, X Meng - Chinese Chemical Letters, 2023 - Elsevier
Benzo [b] thiophene fused compounds with a unique active heterocyclic skeleton have wide
applications in the fields of medicinal chemistry, organic synthesis, and organic functional …

1, 2-Amidoarylcarbonylation of Styrenes to Access β-Acylamino Ketones by NHC-Catalyzed Radical Relay

D Yin, L Lu, Y Jiang, Y Dou, MC Fu… - The Journal of Organic …, 2024 - ACS Publications
An amidoarylcarbonylation reaction of aromatic aldehydes and olefins with Katritzky
pyridinium salts by N-heterocyclic carbene (NHC)-catalyzed radical relay to construct C–C …

[(NHC)Pd(OAc)2]: Highly Active Carboxylate Pd(II)–NHC (NHC = N-Heterocyclic Carbene) Precatalysts for Suzuki–Miyaura and Buchwald–Hartwig Cross-Coupling …

Y Zhu, S Yang, T Zhou, M Szostak - The Journal of Organic …, 2024 - ACS Publications
In the past eight years, the selective cross-coupling of amides by N–C (O) bond activation
has emerged as a highly attractive manifold for the manipulation of traditionally unreactive …

Hypervalent iodine-promoted twofold oxidative coupling of amines with amides and thioamides: chemoselective pathway to oxazoles and thiazoles

J Nan, X Ren, Q Yan, S Liu, J Wang, Y Ma… - Chemical …, 2023 - pubs.rsc.org
Direct functionalization of the C (O)–N amide bond is one of the most high-profile research
directions in the last few decades; however oxidative couplings involving amide bonds and …

Hierarchical NiZn Solid Solution as a Highly Efficient Palladium Free Heterogeneous Catalyst for Suzuki–Miyaura Cross-Coupling Reaction

S Agarwal, S Bairagi, MM Khatun… - ACS Applied Materials & …, 2023 - ACS Publications
In this report, surfactant free solid solution of NiZn with a hierarchical architecture was
synthesized via a one-pot colloidal approach. Evidence supporting hierarchical crystal …