Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Embracing heterogeneous photocatalysis: evolution of photocatalysts in annulation of dimethylanilines and maleimides

Y Liu, R Li, Q Lv, B Yu - Chemical Communications, 2024 - pubs.rsc.org
Recent advances in visible-light-promoted construction of tetrahydroquinolines from
dimethylanilines and maleimides are documented. Homogeneous and heterogeneous …

Single‐atom Fe catalysts for Fenton‐like reactions: roles of different N species

Y Xiong, H Li, C Liu, L Zheng, C Liu… - Advanced …, 2022 - Wiley Online Library
Recognizing and controlling the structure–activity relationships of single‐atom catalysts
(SACs) is vital for manipulating their catalytic properties for various practical applications …

A Redox-Active Supramolecular Fe4L6 Cage Based on Organic Vertices with Acid–Base-Dependent Charge Tunability for Dehydrogenation Catalysis

YL Lu, JQ Song, YH Qin, J Guo, YH Huang… - Journal of the …, 2022 - ACS Publications
Supramolecular cage chemistry is of lasting interest because, as artificial blueprints of
natural enzymes, the self-assembled cage structures not only provide substrate-hosting …

Photoinduced Electron Donor–Acceptor Complex-Mediated Radical Cascade Involving N-(Acyloxy)phthalimides: Synthesis of Tetrahydroquinolines

SK Hota, SP Panda, S Das, SK Mahapatra… - The Journal of …, 2023 - ACS Publications
We conceptualized a novel disconnection approach for the synthesis of fused
tetrahydroquinolines that exploits a visible light-mediated radical (4+ 2) annulation between …

Classic vs. C–H functionalization strategies in the synthesis of APIs: a sustainability comparison

F Ferlin, G Brufani, G Rossini, L Vaccaro - Green Chemistry, 2023 - pubs.rsc.org
The landscape of organic synthesis has changed in the last two decades, especially in
areas such as pharmaceutical synthesis and large-scale industrial synthesis. The progress …

Visible-Light-Induced Cascade Cyclization of 1-Acryloyl-2-cyanoindole: Access of Difluoroalkylated Pyrrolo[1,2-a]indolediones

J Yuan, L Shen, N Guo, Y Yin, P Yang… - The Journal of …, 2023 - ACS Publications
An effective method for accessing diverse difluoroalkylated pyrrolo [1, 2-a] indolediones via
visible-light-induced PhI (OAc) 2-promoted cascade difluoroalkylation/cyclization reaction …

Regioselective, photocatalytic α-functionalization of amines

L Leng, Y Fu, P Liu, JM Ready - Journal of the American Chemical …, 2020 - ACS Publications
Photocatalytic α-functionalization of amines provides a mild and atom-economical means to
synthesize α-branched amines. Prior examples featured symmetrical or electronically biased …

Porphyrin covalent organic framework for photocatalytic synthesis of tetrahydroquinolines

C Wu, X Li, M Shao, J Kan, G Wang, Y Geng… - Chinese Chemical …, 2022 - Elsevier
A metal-free porphyrin covalent organic framework was employed as the heterogeneous
photocatalyst for the synthesis of tetrahydroquinolines under aerobic conditions. With visible …

Missing-linker defects in a covalent organic framework photocatalyst for highly efficient synthesis of tetrahydroquinoline

Y Zhao, K Zhang, K Zhu, Y Zhao, H Zhai, J Qiu - Green Chemistry, 2024 - pubs.rsc.org
Cyclization of N, N-dimethylanilines with maleimides to obtain tetrahydroquinoline
heterocyclic compounds is an essential reaction in industry but it is usually catalyzed by …