Associative thickeners for waterborne paints: Structure, characterization, rheology, and modeling

RG Larson, AK Van Dyk, T Chatterjee… - Progress in Polymer …, 2022 - Elsevier
Architectural coatings/paints play a very important role in our world, making our houses and
workplaces beautiful, comfortable, and energy-efficient. Polymeric components of coating …

Concentration regimes for extensional relaxation times of unentangled polymer solutions

DD Soetrisno, CDV Martínez Narváez, V Sharma… - …, 2023 - ACS Publications
We study the extensional flow properties of polyacrylamide (PAM) solutions with various
molecular weights and dispersities using a dripping-onto-substrate (DoS) protocol. A recent …

Protorheology

MT Hossain, RH Ewoldt - Journal of Rheology, 2024 - pubs.aip.org
We all instinctively poke, bounce, scoop, and observe materials to understand rheological
properties quickly. Yet, these observations are rarely analyzed quantitatively. To address …

Evaporation and rheology chart the processability map for centrifugal force spinning

J Merchiers, CDV Martínez Narváez, C Slykas… - …, 2021 - ACS Publications
We show that poly (ethylene oxide)(PEO) solutions formulated using solvent mixtures of
acetonitrile (AcN) and water can be centrifugally spun into fibers. We find that spinnability …

Solvent properties influence the rheology and pinching dynamics of polyelectrolyte solutions: Thickening the pot with glycerol and cellulose gum

LN Jimenez, CDV Martínez Narváez, V Sharma - Macromolecules, 2022 - ACS Publications
Charge-bearing groups that ionize in solution influence the macromolecular conformations,
interactions, and dynamics of polyelectrolytes. The rich and complex shear rheological …

Heavy metal removal using structured sorbents 3D printed from carbon nanotube-enriched polymer solutions

J Xu, C Slykas, AS Braegelman, KG Alvarez, T Kasl… - Matter, 2022 - cell.com
Sorbents with structures tailored at the molecular through device scales are needed to meet
the demand for separations that can isolate trace analytes from complex mixtures. Here …

Elongational Rheology of Entangled Ionomers Based on Poly (hexyl methacrylate)

S Wu, H Yang, Z Zhang, Q Chen - Macromolecules, 2023 - ACS Publications
Linear viscoelasticity (LVE) and nonlinear elongational behavior are examined for a series
of entangled ionomers based on poly (hexyl methacrylate) as the backbone and sodium …

Rheology and dispensing of real and vegan mayo: the chickpea or egg problem

NN Nikolova, CDVM Narváez, L Hassan, RA Nicholson… - Soft Matter, 2023 - pubs.rsc.org
The rheology, stability, texture, and taste of mayonnaise, a dense oil-in-water (O/W)
emulsion, are determined by interfacially active egg lipids and proteins. Often mayonnaise is …

Extensibility-enriched spinnability and enhanced sorption and strength of centrifugally spun polystyrene fiber mats

J Merchiers, NK Reddy, V Sharma - Macromolecules, 2022 - ACS Publications
We show that incorporating ultrahigh molecular weight (UHMw) polymer fractions into
spinning dopes improves their spinnability and facilitates the centrifugal force spinning …

Temperature-controlled dripping-onto-substrate (DoS) extensional rheometry of polymer micelle solutions

DY Zhang, MA Calabrese - Soft Matter, 2022 - pubs.rsc.org
Capillary-driven thinning of a liquid bridge is commonly used to measure the extensional
rheology of macromolecular solutions for assessment of material sprayability, printability …