Recent applications of gold-catalyzed cascade reactions in total synthesis of natural product

K Sugimoto, Y Matsuya - Tetrahedron Letters, 2017 - Elsevier
From the point of the view of the synthetic efficiency, the concept 'step economy'was required
in total synthesis of natural product. Recently, versatile gold-catalyzed cascade reactions …

Pd-Catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with 3-cyanochromones

I Khan, C Zhao, YJ Zhang - Chemical Communications, 2018 - pubs.rsc.org
An efficient method for the construction of furanobenzodihydropyran skeletons has been
developed through Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene …

Total synthesis of xyloketals and related natural product alboatrin: strategies and tactics

B Panda - ChemistrySelect, 2019 - Wiley Online Library
Abstract Molecular Architectures: Xyloketals are an interesting class of natural products
showing various potent and notable bioactivities like acetylcholine esterase inhibition …

Rapid Construction of Tricyclic Furanobenzodihydropyrans by Asymmetric Tandem Reaction

Y Zhang, J Duan, Y Zhou, X Li, W Yao… - The Journal of Organic …, 2023 - ACS Publications
A process based on the organocatalyzed Mannich/cycloketalization/transesterification
tandem reaction of 1-(2-hydroxyaryl)-1, 3-diketones and β, γ-alkynyl α-imino esters has been …

Gold catalysis: regio-and stereoselective total synthesis of xyloketals D and G and the related natural product alboatrin

B Panda, TK Sarkar - The Journal of Organic Chemistry, 2013 - ACS Publications
A new and efficient one-pot desilylation–gold-catalyzed cycloisomerization of alkynes
containing a silyl-protected phenolic− OH and a free alcoholic− OH unit leads selectively to …

Bioactivity of marine natural product xyloketals

B Panda, AK Gooyee - Letters in Organic Chemistry, 2021 - ingentaconnect.com
Oceans can play a major role in supplying life-saving medicines to the world. Although
considerable progress has been made in finding new medicines from marine sources, great …

Total synthesis and anti-inflammatory evaluation of violacin A and its analogues

Q Liu, Y Mu, Q An, J Xun, J Ma, W Wu, M Xu, J Xu… - Bioorganic …, 2020 - Elsevier
A concise total synthesis of an exceedingly potent anti-inflammatory agent violacin A as well
as the preparation of thirty analogues of this lead from commercially available orcinol are …

Synthesis and structural anomaly of xyloketals‐unique benzoxacycles: A review

B Roy, N Rout, P Kuila, D Sarkar - Journal of Heterocyclic …, 2021 - Wiley Online Library
Xyloketals, unique bioactive compounds, isolated from mangrove fungus Xylaria sp.(no.
2508), having multiple pharmacological, therapeutic properties, have prompted enormous …

Straightforward and highly diastereoselective synthesis of 2, 2-di-substituted perhydrofuro [2, 3-b] pyran (and furan) derivatives promoted by BiCl 3

X Ma, Q Tang, J Ke, J Zhang, C Wang… - Chemical …, 2013 - pubs.rsc.org
An effective and facile method for the synthesis of 2, 2-di-substituted perhydrofuro [2, 3-b]
pyran (and furan) derivatives is described. The cyclization of 1, 2-cyclopropanated sugars …

A neighboring group participation strategy: direct and highly diastereoselective synthesis of 2-substituted and 2, 2-bisubstituted perhydrofuro [2, 3-b] pyran derivatives

X Ma, Q Tang, J Ke, J Zhang, X Yang, X Shen… - Organic & Biomolecular …, 2014 - pubs.rsc.org
Treatment of methyl 2-C-formylmethyl-2-deoxy-β-D-glucopyranoside (5) or methyl 2-C-
acetylmethyl-2-deoxy-β-D-glucopyranoside (1) with H2SO4–HOAc–Ac2O gave 2-acetoxyl-4 …