Kinetics of Intercluster Reactions between Atomically Precise Noble Metal Clusters [Ag25(DMBT)18] and [Au25(PET)18] in Room Temperature Solutions

M Neumaier, A Baksi, P Weis… - Journal of the …, 2021 - ACS Publications
The kinetics of intercluster metal atom exchange reactions between solvated [Ag25 (DMBT)
18]− and [Au25 (PET) 18]−(DMBT and PET are 2, 4-dimethylbenzenethiol and 2 …

Chiroptical activity of Au 13 clusters: experimental and theoretical understanding of the origin of helical charge movements

Y Shichibu, Y Ogawa, M Sugiuchi, K Konishi - Nanoscale advances, 2021 - pubs.rsc.org
Ligand-protected gold clusters with an asymmetric nature have emerged as a novel class of
chiral compounds, but the origins of their chiroptical activities associated with helical charge …

“Sergeants-and-soldiers” principle in the synthesis of intrinsically chiral Au 13 clusters

K Mutoh, S Kawakita, T Yahagi, T Nakashima - Nanoscale, 2024 - pubs.rsc.org
Surface ligand modification on atomically precise metal clusters is one of the important
strategies not only to stabilize monodisperse clusters but also to derive unique optical and …

Insights into the effect of regulation of molecular composition on the properties of (AuAg) 9 clusters

X Yan, S Su, X Li, S Jin, M Zhu - Dalton Transactions, 2023 - pubs.rsc.org
The precise tuning of cluster composition helps us to understand the relationship between
clusters and their properties. In this context, on the basis of [Au4Ag5 (SAdm) 6 (Dppm) …

Combined spectroscopic studies on post-functionalized Au 25 cluster as an ATR-FTIR sensor for cations

A Baghdasaryan, E Brun, Y Wang, G Salassa… - Chemical …, 2021 - pubs.rsc.org
Recently, significant research activity has been devoted to thiolate-protected gold clusters
due to their attractive optical and electronic properties. These properties as well as solubility …

Revealing the electronic properties of the B–B bond: the bis-catecholato diboron molecule

D Toffoli, C Grazioli, M Monti, M Stener… - Physical Chemistry …, 2021 - pubs.rsc.org
The electronic properties of a diboron molecule, namely bis (catecholato) diboron (2-(1, 3, 2-
benzodioxaborol-2-yl)-1, 3, 2-benzodioxaborole)(B2Cat2), have been studied by comparing …

Total structural determination of alloyed Au 15.37 Cu 16.63 (S-Adm) 20 nanoclusters with double superatomic chains

L Tang, S Deng, S Wang, Y Pei, M Zhu - Chemical Communications, 2021 - pubs.rsc.org
Thiolated-alloy nanocluster Au15. 37Cu16. 63 (S-Adm) 20 ((AuCu) 32 for short) has been
synthesized. Single crystal X-ray crystallography (SC-XRD) proved that this cluster contains …

Estudo computacional de nanoestruturas de ouro funcionalizadas com moléculas orgânicas quirais

ACA Silva - 2023 - repositorio.ufscar.br
A nanociência é uma área recente de caráter interdisciplinar e que fundamentalmente
estuda materiais cuja suas dimensões se encontram em escala em escala nanométrica, ou …

Computational approaches to the study of the electronic properties, structure and functionalization of metal nanoparticles

D Rapetti - 2021 - tesidottorato.depositolegale.it
In this thesis, we developed and used different computational techniques to study the
physicochemical properties of metal nanoparticles. We studied both bare nanoparticles and …