The possible role of metal carbonyl clusters in nanoscience and nanotechnologies

C Femoni, MC Iapalucci, F Kaswalder… - Coordination chemistry …, 2006 - Elsevier
Although a few nanosized metal carbonyl clusters were already obtained in the seventies,
these structurally and compositionally well-defined molecules attracted the interest of …

Metal–metal and metal–ligand bond strengths in metal carbonyl clusters

AK Hughes, K Wade - Coordination Chemistry Reviews, 2000 - Elsevier
The limited experimental thermochemical information about metal carbonyl clusters, and the
more extensive literature on structural studies of such compounds, provide a means of …

Atomically precise rhodium–indium carbonyl nanoclusters: synthesis, characterization, crystal structure and electron-sponge features

G Bussoli, A Boccalini, M Bortoluzzi, C Cesari… - Nanoscale, 2024 - pubs.rsc.org
In this paper we present the investigation of the reactivity of [Rh7 (CO) 16] 3− with InCl3, with
the aim of expanding the more general study that allowed us to obtain, among other species …

Vibrational study of some layered structures based on titanium and zirconium phosphates

PL Stanghellini, E Boccaleri, E Diana, G Alberti… - Inorganic …, 2004 - ACS Publications
A Raman and infrared study was carried out on layered zirconium and titanium acid
phosphates of α-and γ-type, α-M [O3POH] 2⊙ H2O and γ-M [PO4][O2P (OH) 2]⊙ 2H2O …

Spectroscopic and mass spectrometric methods for the characterisation of metal clusters

S McIndoe - Coordination Chemistry Reviews, 2000 - Elsevier
This review covers some of the many spectroscopic and mass spectrometric techniques
used to characterise transition metal clusters. Special attention has been paid to recent …

Advances in the chemistry of alkyne-substituted homo-and heterometallic carbonyl clusters of the iron, cobalt and nickel triads. An update

G Gervasio, E Sappa, A Secco - Journal of Organometallic Chemistry, 2014 - Elsevier
Recent developments in the chemistry of homo-and heterometallic clusters of Iron, Cobalt
and Nickel triads substituted with alkynes and related ligands are examined. New synthetic …

Comprehensive spectral and instrumental approaches for the easy monitoring of features and purity of different carbon nanostructures for nanocomposite applications

E Boccaleri, A Arrais, A Frache, W Gianelli… - Materials Science and …, 2006 - Elsevier
A wide series of carbon nanostructures (ranging from fullerenes, through carbon nanotubes,
up to carbon nanofibers) promise to change several fields in material science, but a real …

Mass spectrometric method for the rapid characterization of transition metal carbonyl cluster reaction mixtures

PJ Dyson, AK Hearley, BFG Johnson, T Khimyak… - …, 2001 - ACS Publications
Energy-dependent electrospray ionization mass spectrometry (EDESI-MS) has been applied
to the characterization of reaction products that contain a mixture of metal carbonyl cluster …

Transition metal carbonyl clusters in biology: A futile or niche research area?

A Arrais, E Gabano, M Ravera, D Osella - Inorganica Chimica Acta, 2018 - Elsevier
Transition metal carbonyl clusters (TMCCs) have seldom been considered in a biological
perspective. Albeit generally flawed with low water-solubility and poor air-stability …

Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [Rh …

A Boccalini, PJ Dyson, C Femoni, MC Iapalucci… - Dalton …, 2018 - pubs.rsc.org
The reaction of the [Rh7 (CO) 16] 3− cluster anion with Ge2+ salts, in different stoichiometric
ratios and under different atmospheres, leads to the formation of new heterometallic Rh–Ge …