The use of synchrotron radiation in X-ray charge density analysis of coordination complexes
The compelling advantages of synchrotron radiation (SR) in charge density studies of
coordination complexes are described and illustrated with a number of recent synchrotron …
coordination complexes are described and illustrated with a number of recent synchrotron …
Pentadienyl complexes of the group 4 transition metals
Publisher Summary This chapter focuses on the advances made in the pentadienyl
chemistry of three elements—namely, titanium, zirconium, and hafnium. As group 4 …
chemistry of three elements—namely, titanium, zirconium, and hafnium. As group 4 …
Reactions of SF6 with Organotitanium and Organozirconium Complexes: The “Inert” SF6 as a Reactive Fluorinating Agent
R Basta, BG Harvey, AM Arif… - Journal of the American …, 2005 - ACS Publications
The normally remarkably inert SF6 has been found to be quite reactive toward low valent
organometallic compounds, under conditions in which usually powerful fluorinating agents …
organometallic compounds, under conditions in which usually powerful fluorinating agents …
Investigation of Zr− C, Zr− N, and potential agostic interactions in an organozirconium complex by experimental electron density analysis
S Pillet, G Wu, V Kulsomphob, BG Harvey… - Journal of the …, 2003 - ACS Publications
The crystal structure and electron density (ED) distribution of an imine coupling product with
an open zirconocene, Zr (2, 4-C7H11)[(i-Pr) NCHPhCH2CMe CHCMe CH2](C7H11 …
an open zirconocene, Zr (2, 4-C7H11)[(i-Pr) NCHPhCH2CMe CHCMe CH2](C7H11 …
Cp2Zr(η2-benzocyclobutadiene)(PMe3), a Rare η2-Cyclobutadiene Complex
TVV Ramakrishna, S Lushnikova, PR Sharp - Organometallics, 2002 - ACS Publications
Cp2Zr(η2-benzocyclobutadiene)(PMe3), a Rare η2-Cyclobutadiene Complex | Organometallics
ACS ACS Publications C&EN CAS Find my institution Log In Organometallics ACS Publications …
ACS ACS Publications C&EN CAS Find my institution Log In Organometallics ACS Publications …
Mono (cyclopentadienyl) titanium (II) complexes with hydride, alkyl, and tetrahydroborate ligands: Synthesis, crystal structures, and ethylene dimerization and …
Y You, GS Girolami - Organometallics, 2008 - ACS Publications
The mono (cyclopentadienyl) titanium (II) complex CpTiCl (dmpe) 2 has been prepared by
treating (CpTiCl2) x with n-butyllithium in the presence of 1, 2-bis (dimethylphosphino) …
treating (CpTiCl2) x with n-butyllithium in the presence of 1, 2-bis (dimethylphosphino) …
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+ (L = xylNC, t …
WS Ojo, FY Pétillon, P Schollhammer… - Organometallics, 2008 - ACS Publications
Reductive coupling between isocyanide ligands attached to adjacent molybdenum atoms in
the bis (aryl isocyanide) complex [Mo2Cp2 (μ-SMe) 3 (xylNC) 2](BF4)(1) was initiated by …
the bis (aryl isocyanide) complex [Mo2Cp2 (μ-SMe) 3 (xylNC) 2](BF4)(1) was initiated by …
Nature of the metal–carbon contacts in ene-diamido d 0 metal complexes
Folding of ene-diamido chelates in d0 metal complexes is generally attributed to a saturating
π interaction of the metal with the central CC linkage. A MO analysis of selected models …
π interaction of the metal with the central CC linkage. A MO analysis of selected models …
Unexpected Coupling of Cp and Two RNC Ligands at a {Mo2(μ-SMe)3} Nucleus
N Cabon, E Paugam, FY Pétillon… - …, 2003 - ACS Publications
Reaction of the bis-isonitrile complex [Mo2Cp2 (μ-SMe) 3 (t-BuNC) 2](BF4)(1) with n-BuLi (in
hexane) produced the dealkylated derivative [Mo2Cp2 (μ-SMe) 3 (t-BuNC)(CN)](2) in …
hexane) produced the dealkylated derivative [Mo2Cp2 (μ-SMe) 3 (t-BuNC)(CN)](2) in …
Zr (C5H5)(6, 6-dmch)(PMe3) 2, an edge-bridged half-open zirconocene—synthesis, structure, and its reaction with C6H5C2SiMe3
The synthesis and characterization of an edge-bridged half-open zirconocene, Zr
(C5H5)(dmch)(PMe3) 2 (dmch= dimethylcyclohexadienyl), are described. As expected, the …
(C5H5)(dmch)(PMe3) 2 (dmch= dimethylcyclohexadienyl), are described. As expected, the …