Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Chirality of molecular nanostructures on surfaces via molecular assembly and reaction: manifestation and control

Y Xu, JJ Duan, ZY Yi, KX Zhang, T Chen… - Surface Science Reports, 2021 - Elsevier
The formation of chiral nanostructures via molecular assembly and reaction on solid
surfaces is a ubiquitous surface process due to the symmetry-breaking at 2D surface …

Synthesis of a Porous [14] Annulene Graphene Nanoribbon and a Porous [30] Annulene Graphene Nanosheet on Metal Surfaces

T Qin, D Guo, J Xiong, X Li, L Hu… - Angewandte Chemie …, 2023 - Wiley Online Library
The electrical and mechanical properties of graphene‐based materials can be tuned by the
introduction of nanopores, which are sensitively related to the size, morphology, density, and …

Tuning the diradical character of pentacene derivatives via non-benzenoid coupling motifs

T Wang, P Angulo-Portugal… - Journal of the …, 2023 - ACS Publications
The development of functional organic molecules requires structures of increasing size and
complexity, which are typically obtained by the covalent coupling of smaller building blocks …

Confined on-surface organic synthesis: Strategies and mechanisms

T Wang, J Zhu - Surface Science Reports, 2019 - Elsevier
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …

Kinetic strategies for the formation of graphyne nanowires via Sonogashira coupling on Ag (111)

T Wang, J Huang, H Lv, Q Fan, L Feng… - Journal of the …, 2018 - ACS Publications
The selection of a reaction pathway with high energy barrier in a multipath on-surface
reaction system has been challenging. Herein, we report the successful control of the …

Steering On-Surface Reactions by Kinetic and Thermodynamic Strategies

T Wang, Q Fan, J Zhu - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
On-surface synthesis has emerged as a powerful tool to fabricate various functional low-
dimensional nanostructures with atomic precision, thus becoming a promising platform for …

Dramatic acceleration of the Hopf cyclization on gold (111): From enediynes to peri-fused diindenochrysene graphene nanoribbons

C Zhao, DD Bhagwandin, W Xu… - Journal of the …, 2024 - ACS Publications
Hopf et al. reported the high-temperature 6π-electrocyclization of cis-hexa-1, 3-diene-5-yne
to benzene in 1969. Subsequent studies using this cyclization have been limited by its very …

Metal‐Free and Redox‐Neutral Conversion of Organotrifluoroborates into Radicals Enabled by Visible Light

W Liu, P Liu, L Lv, CJ Li - Angewandte Chemie, 2018 - Wiley Online Library
Converting organoboron compounds into the corresponding radicals has broad synthetic
applications in organic chemistry. To achieve these transformations, various strong oxidants …

On-surface synthesis of enetriynes

N Cao, B Yang, A Riss, J Rosen, J Björk… - Nature …, 2023 - nature.com
Belonging to the enyne family, enetriynes comprise a distinct electron-rich all-carbon
bonding scheme. However, the lack of convenient synthesis protocols limits the associated …