Coordinative Chain Transfer and chain shuttling polymerization

R Mundil, C Bravo, N Merle, P Zinck - Chemical Reviews, 2023 - ACS Publications
Coordinative chain transfer polymerization, CCTP, is a degenerative chain transfer
polymerization process that has a wide range of applications. It allows a highly controlled …

Measurement Techniques and Methods for the Pressure Coefficient of Viscosity of Polymer Melts

Y Liao, Y Hu, Y Tan, K Ikeda, R Okabe… - Advances in Polymer …, 2023 - Wiley Online Library
Viscosity is a prominent rheological property of polymer, which is affected by temperature,
pressure, shear rate, molecular structure, and other factors. Despite the importance of the …

Ring repeating unit: an upgraded structure representation of linear condensation polymers for property prediction

M Yu, Y Shi, Q Jia, Q Wang, ZH Luo… - Journal of Chemical …, 2023 - ACS Publications
Unique structure representation of polymers plays a crucial role in developing models for
polymer property prediction and polymer design by data-centric approaches. Currently …

Synthesis of Statistical Multiblock Copolymers through Chain Shuttling Copolymerization with a Thermomechanical Switch Behavior

A Vittoria, G Urciuoli, S Costanzo, V Ianniello… - …, 2024 - ACS Publications
A high-throughput experimentation (HTE) approach is adopted for the synthesis of a special
class of elastomeric polyolefins with a tailored thermomechanical response …

Molecular Architecture of Multiblock Copolymers Synthesized by the Chain Shuttling Technology

G Urciuoli, O Ruiz de Ballesteros… - … Chemistry and Physics, 2023 - Wiley Online Library
Recent advances in the characterization of ethylene/1‐octene‐based statistical multiblock
copolymers (MBCs) synthesized via chain shuttling copolymerization are illustrated. The …

End-to-End High-Throughput Approach for Data-Driven Internal Donor Development in Heterogeneous Ziegler–Natta Propylene Polymerization

T Taniike, FD Cannavacciuolo, M Khoshsefat… - ACS …, 2024 - ACS Publications
Internal donors (IDs) play a decisive role in shaping the structure and performance of Ziegler–
Natta catalyst formulations for isotactic polypropylene production. Unfortunately, their …

Parallel Catalyst Synthesis Protocol for Accelerating Heterogeneous Olefin Polymerization Research

P Chammingkwan, M Khoshsefat, M Terano, T Taniike - Polymers, 2023 - mdpi.com
The data scientific approach has become an indispensable tool for capturing structure–
performance relationships in complex systems, where the quantity and quality of data play a …

Aluminum Alkyl Induced Isomerization of Group IV meso Metallocene Complexes

TM Lenz, I Chiorescu, FE Napoli… - Angewandte Chemie …, 2024 - Wiley Online Library
The synthesis of group IV metallocene precatalysts for the polymerization of propylene
generally yields two different isomers: The racemic isomer that produces isotactic …

Effect of Segregation Strength on Mesophase Separation in Statistical Multiblock Copolymers Synthesized through a High-Throughput Experimentation Approach

G Urciuoli, A Vittoria, FD Cannavacciuolo… - …, 2023 - ACS Publications
Ethylene/hex-1-ene (E/H) statistical multiblock copolymers (MBCs) with molecular mass
between 144 and 188 kDa, and segregation strength greater than that of commercially …

Convergence of Artificial Intelligence, Machine Learning, Cheminformatics, and Polymer Science in Macromolecules

A Jayaraman, B Olsen - Macromolecules, 2024 - ACS Publications
Over the past decade, it has become abundantly clear that there is no escaping the
emerging growth of artificial intelligence (AI) in every facet of our life. The advanced …