Being the third most abundant transition metal in the Earth's crust (after iron and titanium)
and less toxic, reactions catalyzed by manganese are becoming very important. A large …

Conspectus In recent years, interest in homogeneous manganese catalyst development has
intensified because of the earth-abundant and nontoxic nature of this metal. Although …

The first example of room temperature non-noble metal homogeneous system catalyzed
selective N-alkylation of anilines with alcohols by a bis-NHC manganese complex is …

The selective mono-N-methylation of anilines derivatives was achieved under mild
conditions using inexpensive methanol as C1 source. Under hydrogen borrowing …

Herein, we report a very simple and inexpensive catalytic system based on Earth's abundant
transition metal manganese and on a bench‐stable phosphine‐free NNN‐pincer ligand for …

A very simple and inexpensive catalytic system based on abundant manganese as transition
metal and on an inexpensive phosphine-free bidendate ligand, 2-(aminomethyl) pyridine …

The direct α-methylation of ketones with methanol under hydrogen borrowing conditions
using a well-defined manganese PN3P complex as a pre-catalyst was, for the first time …

Recent developments in manganese-catalyzed reducing transformations—hydrosilylation,
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …

Herein, we disclose the first manganese‐catalyzed hydrosilylation of alkynes featuring
diverse selectivities. The highly selective formation of E‐products was achieved by using …

The present paper comprehensively reviews group 3–7 metal NHC complexes reported
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …