Advances on the merger of electrochemistry and transition metal catalysis for organic synthesis

CA Malapit, MB Prater, JR Cabrera-Pardo, M Li… - Chemical …, 2021 - ACS Publications
Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Convergent deboronative and decarboxylative phosphonylation enabled by the phosphite radical trap “BecaP”

SK Pagire, C Shu, D Reich, A Noble… - Journal of the …, 2023 - ACS Publications
Carbon–phosphorus bond formation is significant in synthetic chemistry because
phosphorus-containing compounds offer numerous indispensable biochemical roles. While …

Surface modification using phosphonic acids and esters

C Queffélec, M Petit, P Janvier, DA Knight… - Chemical …, 2012 - ACS Publications
1. INTRODUCTION The design of organically modified surfaces is a rapidly expanding field
of research in materials science in which the central purpose is access to materials …

Regio-and stereoselective access to highly substituted vinylphosphine oxides via metal-free electrophilic phosphonoiodination of alkynes

B Dong, F Zhao, WX Lv, YG Liu, D Wei, J Wu… - Nature …, 2024 - nature.com
In general, the P-centered ring-opening of quaternary phosphirenium salts (QPrS)
predominantly leads to hydrophosphorylated products, while the C-centered ring-opening is …

Nickel-catalyzed enantioconvergent reductive hydroalkylation of olefins with α-heteroatom phosphorus or sulfur alkyl electrophiles

SJ He, JW Wang, Y Li, ZY Xu, XX Wang… - Journal of the …, 2019 - ACS Publications
Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formation reactions have
been made in recent years through the use of transition-metal-catalyzed cross-coupling …

Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis

Q Fu, ZY Bo, JH Ye, T Ju, H Huang, LL Liao… - Nature …, 2019 - nature.com
Catalytic difunctionalization of alkenes has been an ideal strategy to generate structurally
complex molecules with diverse substitution patterns. Although both phosphonyl and …

Visible‐Light Photoredox‐Catalyzed Remote Difunctionalizing Carboxylation of Unactivated Alkenes with CO2

L Song, DM Fu, L Chen, YX Jiang, JH Ye… - Angewandte Chemie …, 2020 - Wiley Online Library
Remote difunctionalization of unactivated alkenes is challenging but a highly attractive tactic
to install two functional groups across long distances. Reported herein is the first remote …

Electrochemically dehydrogenative C–H/P–H cross-coupling: effective synthesis of phosphonated quinoxalin-2 (1 H)-ones and xanthenes

KJ Li, YY Jiang, K Xu, CC Zeng, BG Sun - Green Chemistry, 2019 - pubs.rsc.org
An efficient electrochemical approach for the C (sp2)–H phosphonation of quinoxalin-2 (1H)-
ones and C (sp3)–H phosphonation of xanthenes has been developed. The chemistry was …

Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis

X Li, M Yuan, F Chen, Z Huang, FL Qing, O Gutierrez… - Chem, 2023 - cell.com
The development of efficient catalytic multicomponent reactions (MCRs) is highly sought-
after in chemical synthesis. However, catalytic asymmetric MCRs, particularly involving …