As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Carbon–hydrogen bond functionalizations provide an attractive method for streamlining
organic synthesis, and many strategies have been developed for conducting these …

A stereo-and enantioselective benzylic C–H alkenylation via photoredox/nickel catalysis is
reported. Readily available alkylbenzenes and alkenyl bromides including complicated …

Catalytic asymmetric electrochemical C–H functionalization of simple ketones has been
developed. The transformation is realized by the combination of electrochemical oxidation …

Highly enantioselective gold‐catalyzed intramolecular cyclization of N‐allenamides was
implemented by utilizing a designed chiral sulfinamide phosphine ligand (PC‐Phos). This …

The combination of photoredox catalysis and enamine catalysis has enabled the
development of an enantioselective aerobic oxidative cross-dehydrogenative coupling …

N, O-aminals, molecules bearing a geminally N, O-substituted (stereogenic) carbon center,
have been recently recognized as an important class of building blocks in organic synthesis …

A cooperative photoredox and asymmetric catalysis for the enantioselective aerobic
oxidative C (sp3)–H olefination of tetrahydro-β-carbolines (THCs) is reported. This method …

We report here a concise, collective, and asymmetric total synthesis of sarpagine alkaloids
and biogenetically related koumine alkaloids, which structurally feature a rigid cage scaffold …

A method for the C (sp3)–H alkenylation of N-aryl-tetrahydroisoquinoline (THIQ) has been
developed by the combination of electrooxidation and a copper catalyst. The corresponding …