Single-atom catalysts (SACs) include a promising family of electrocatalysts with unique
geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging …

Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

Structural transformation and evolution of active metal sites can occur in metal-catalyzed
reactions in both homogeneous and heterogeneous systems. Such structural changes have …

The design of organometallic catalysts is crucial in the development of catalytic reactions.
Herein, we describe a heterometallic [Os-Cu] complex with the characteristics of bimetallics …

There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

One of the most challenging tasks in organic synthesis is to control selectivities, especially
switching the well-known selectivity to obtain new isomers that were previously inaccessible …

Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …

We report the magnesiation of aryl fluorides catalyzed by an Al–Rh heterobimetallic
complex. We show that the complex is highly reactive to cleave the C–F bonds across the …

Ligands are known to play a crucial role in the construction of complexes with metal–metal
bonds. Compared with metal–metal bonds involving d-block transition metals, knowledge of …

We report the preparation and characterization of the dinuclear AuII hydroxide complex
AuII2 (L) 2 (OH) 2 (L= N, N′‐bis (2, 6‐dimethyl) phenylformamidinate) and study its …