Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities

W Ahn, JF Triana, F Recabal, F Herrera, BS Simpkins - Science, 2023 - science.org
Reaction-rate modifications for chemical processes due to strong coupling between reactant
molecular vibrations and the cavity vacuum have been reported; however, no currently …

Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry

JA Campos-Gonzalez-Angulo, YR Poh, M Du… - The Journal of …, 2023 - pubs.aip.org
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …

RETRACTED: Solvent polarity under vibrational strong coupling

M Piejko, B Patrahau, K Joseph, C Muller… - Journal of the …, 2023 - ACS Publications
Vibrational strong coupling (VSC) occurs when molecular vibrations hybridize with the
modes of an optical cavity, an interaction mediated by vacuum fluctuations. VSC has been …

Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation

TT Chen, M Du, Z Yang, J Yuen-Zhou, W Xiong - Science, 2022 - science.org
Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons
yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …

Suppression and enhancement of thermal chemical rates in a cavity

J Sun, O Vendrell - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
The observed modification of thermal chemical rates in Fabry–Perot cavities remains a
poorly understood effect theoretically. Recent breakthroughs explain some of the …

Tuning the coherent propagation of organic exciton‐polaritons through dark state delocalization

R Pandya, A Ashoka, K Georgiou, J Sung… - Advanced …, 2022 - Wiley Online Library
While there have been numerous reports of long‐range polariton transport at room‐
temperature in organic cavities, the spatiotemporal evolution of the propagation is scarcely …