Here, we review the design of optical cavities, transient and modulated responses, and theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
Reaction-rate modifications for chemical processes due to strong coupling between reactant molecular vibrations and the cavity vacuum have been reported; however, no currently …
In this review, we present the theoretical foundations and first-principles frameworks to describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
The coherent exchange of energy between materials and optical fields leads to strong light– matter interactions and so-called polaritonic states with intriguing properties, halfway …
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
Vibrational strong coupling (VSC) occurs when molecular vibrations hybridize with the modes of an optical cavity, an interaction mediated by vacuum fluctuations. VSC has been …
Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …
J Sun, O Vendrell - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
The observed modification of thermal chemical rates in Fabry–Perot cavities remains a poorly understood effect theoretically. Recent breakthroughs explain some of the …
While there have been numerous reports of long‐range polariton transport at room‐ temperature in organic cavities, the spatiotemporal evolution of the propagation is scarcely …