London dispersion in molecular chemistry—reconsidering steric effects

JP Wagner, PR Schreiner - Angewandte Chemie International …, 2015 - Wiley Online Library
London dispersion, which constitutes the attractive part of the famous van der Waals
potential, has long been underappreciated in molecular chemistry as an important element …

London'sche Dispersionswechselwirkungen in der Molekülchemie–eine Neubetrachtung sterischer Effekte

JP Wagner, PR Schreiner - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Die London'sche Dispersion, die den attraktiven Teil des Van‐der‐Waals‐
Potentials beschreibt, wurde lange als Element struktureller Stabilität in der molekularen …

Unraveling non-covalent interactions within flexible biomolecules: from electron density topology to gas phase spectroscopy

R Chaudret, B De Courcy, J Contreras-Garcia… - Physical Chemistry …, 2014 - pubs.rsc.org
The NCI (Non-Covalent Interactions) method, a recently-developed theoretical strategy to
visualize weak non-covalent interactions from the topological analysis of the electron density …

The generalized invariom database (GID)

B Dittrich, CB Huebschle, K Proepper… - … Section B: Structural …, 2013 - scripts.iucr.org
Invarioms are aspherical atomic scattering factors that enable structure refinement of more
accurate and more precise geometries than refinements with the conventional independent …

A combined Raman-and infrared jet study of mixed methanol–water and ethanol–water clusters

M Nedić, TN Wassermann, RW Larsen… - Physical Chemistry …, 2011 - pubs.rsc.org
The vibrational dynamics of vacuum-isolated hydrogen-bonded complexes between water
and the two simplest alcohols is characterized at low temperatures by Raman and FTIR …

Femtisecond single-mole infrared spectroscopy of molecular clusters

MA Suhm, F Kollipost - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
The sensitivity limitations of Fourier transform infrared (FTIR) spectroscopy for the detection
of molecular clusters formed in rarefied gas expansions can be overcome by synchronizing …

Rovibronic signatures of molecular aggregation in the gas phase: subtle homochirality trends in the dimer, trimer and tetramer of benzyl alcohol

R Medel, A Camiruaga, RT Saragi, P Pinacho… - Physical Chemistry …, 2021 - pubs.rsc.org
Molecular aggregation is of paramount importance in many chemical processes, including
those in living beings. Thus, characterization of the intermolecular interactions is an …

The role of weak hydrogen bonds in chiral recognition

D Scuderi, K Le Barbu-Debus… - Physical Chemistry …, 2011 - pubs.rsc.org
Chiral recognition has been studied in neutral or ionic weakly bound complexes isolated in
the gas phase by combining laser spectroscopy and quantum chemical calculations. Neutral …

Dispersion Control over Molecule Cohesion: Exploiting and Dissecting the Tipping Power of Aromatic Rings

RA Mata, T Zhanabekova, DA Obenchain… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus We have learned over the past years how London dispersion forces can be
effectively used to influence or even qualitatively tip the structure of aggregates and the …

Photochemical synthesis of oligomeric amphiphiles from alkyl oxoacids in aqueous environments

RJ Rapf, RJ Perkins, H Yang, GM Miyake… - Journal of the …, 2017 - ACS Publications
The aqueous phase photochemistry of a series of amphiphilic α-keto acids with differing
linear alkyl chain lengths was investigated, demonstrating the ability of sunlight-initiated …