Recent advances in heterocyclic nanographenes and other polycyclic heteroaromatic compounds

A Borissov, YK Maurya, L Moshniaha… - Chemical …, 2021 - ACS Publications
This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

Chiroptical properties of symmetric double, triple, and multiple helicenes

T Mori - Chemical Reviews, 2021 - ACS Publications
Helicenes have attracted considerable attention due to their inherent helical chirality and
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …

Helical Synthetic Nanographenes with Atomic Precision

Y Zhu, J Wang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding and harnessing the properties of nanoscale molecular entities
are considered as new frontiers in basic chemistry. In this regard, synthetic nanographene …

Inducing single-handed helicity in a twisted molecular nanoribbon

RK Dubey, M Melle-Franco… - Journal of the American …, 2022 - ACS Publications
Molecular conformation has an important role in chemistry and materials science. Molecular
nanoribbons can adopt chiral twisted helical conformations. However, the synthesis of single …

A Near‐Infrared Absorbing and Emissive Quadruple Helicene Enabled by the Scholl Reaction of Perylene

SH Pun, KM Cheung, D Yang, H Chen… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, we report the synthesis, structural analysis, optical and chiroptical properties of a
novel quadruple helicene, which has two [6] and two [7] helicene moieties fused in a …

Nitrogen-embedded quintuple [7] helicene: a helicene–azacorannulene hybrid with strong near-infrared fluorescence

YF Wu, SW Ying, LY Su, JJ Du, L Zhang… - Journal of the …, 2022 - ACS Publications
Herein, a nitrogen-embedded quintuple [7] helicene (N-Q7H) with an
azapentabenzocorannulene core, which can be considered to be a helicene …

Double π‐extended undecabenzo [7] helicene

Y Chen, C Lin, Z Luo, Z Yin, H Shi… - Angewandte Chemie …, 2021 - Wiley Online Library
This work reports the first double π‐extended undecabenzo [7] helicene 1, which is a large
chiral nanographene, composed of 65 fused rings and 186 conjugated carbon atoms. The …

Twisted molecular nanoribbons with up to 53 linearly-fused rings

RK Dubey, M Melle-Franco… - Journal of the American …, 2021 - ACS Publications
The synthesis of three molecular nanoribbons with a twisted aromatic framework is
described. The largest one shows a 53 linearly fused rings backbone (12.9 nm) and 322 …

A family of superhelicenes: Easily tunable, chiral nanographenes by merging helicity with planar π systems

D Reger, P Haines, KY Amsharov… - Angewandte …, 2021 - Wiley Online Library
We designed a straightforward synthetic route towards a full‐fledged family of π‐extended
helicenes: superhelicenes. They have two hexa‐peri‐hexabenzocoronenes (HBCs) in …

Multiple helicenes featuring synthetic approaches and molecular structures

A Tsurusaki, K Kamikawa - Chemistry Letters, 2021 - academic.oup.com
Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …