Recent advances in the hydrosilylation and related reactions

I Ojima, Z Li, J Zhu - The chemistry of organic silicon …, 1998 - Wiley Online Library
Hydrosilylation, especially of carbon carbon multiple bonds, is one of the most important
reactions in organosilicon chemistry, and thus the reaction has been studied extensively for …

Metal-Free hydrosilylation polymerization by merging photoredox and hydrogen atom transfer catalysis

Z Huang, Z Chen, Y Jiang, N Li, S Yang… - Journal of the …, 2021 - ACS Publications
Organosilicon compounds and polymers have found wide applications as synthetic building
blocks and functional materials. Hydrosilylation is a common strategy toward the synthesis of …

Metal‐Free Hydrosilylation Polymerization by Borane Catalyst

DW Kim, S Joung, JG Kim… - Angewandte Chemie …, 2015 - Wiley Online Library
The first example of metal‐free hydrosilylation polymerization between dienes and disilanes
is developed by using a borane catalyst, B (C6F5) 3 to replace precious transition‐metal …

Hybrid organic/inorganic copolymers with strongly hydrogen-bond acidic properties for acoustic wave and optical sensors

JW Grate, SN Kaganove, SJ Patrash… - Chemistry of …, 1997 - ACS Publications
Hybrid organic/inorganic polymers have been prepared incorporating fluoroalkyl-substituted
bisphenol groups linked using oligosiloxane spacers. These hydrogen-bond acidic …

Transition Metal-Catalyzed Synthesis of Silicon Polymers.

H Yamashita, M Tanaka - Bulletin of the Chemical Society of Japan, 1995 - jlc.jst.go.jp
Si–H and Si–Si bonds are efficiently transformed by early and late transition metal catalyses
that involve possible key elemental steps, such as σ-bond metathesis, the oxidative addition …

Polysilalkylene or silarylene siloxanes said hybrid silicones

F Guida-Pietrasanta, B Boutevin, O Nuyken… - Inorganic polymeric …, 2005 - Springer
This paper reviews different methods of synthesis of polysilalkylene or silarylene
siloxanesthat are sometimes called “hybrid” silicones. This special type of silicone has …

PAMAMOS: The first commercial silicon‐containing dendrimers and their applications

PR Dvornic - Journal of Polymer Science Part A: Polymer …, 2006 - Wiley Online Library
The world of dendrimers presently encompasses several thousands of publications,
including scientific papers and patents, several hundreds of different compositions, but only …

Facile synthesis of cyclosiloxane-based polymers for hybrid film formation

A Demirci, S Yamamoto, J Matsui, T Miyashita… - Polymer …, 2015 - pubs.rsc.org
A straightforward synthesis of cyclosiloxane-based hybrid polymers and preparation of
hybrid network polymer films were demonstrated. Cyclosiloxane-based hybrid polymers …

Thermal degradation of poly(dimethylsilylene) and poly(tetramethyldisilylene‐co‐styrene)

TS Radhakrishnan - Journal of applied polymer science, 2006 - Wiley Online Library
Thermal degradation of poly (dimethylsilylene) homopolymer (PDMS) and poly
(tetramethyldisilylene‐co‐styrene) copolymer (PTMDSS) was investigated by pyrolysis‐gas …

Linear and branched alkyl substituted octakis (dimethylsiloxy) octasilsesquioxanes: WAXS and thermal properties

FX Perrin, TBV Nguyen, A Margaillan - European polymer journal, 2011 - Elsevier
A series of octakis (dimethylsiloxy) octasilsesquioxanes bearing linear and branched alkyl
substituents has been prepared in high yield by Pt-catalyzed hydrosilylation of alkenes with …