From lithium to emerging mono-and multivalent-cation-based rechargeable batteries: non-aqueous organic electrolyte and interphase perspectives

H Zhang, L Qiao, H Kühnle, E Figgemeier… - Energy & …, 2023 - pubs.rsc.org
Since the oil crisis in the 1970s, the importance of rechargeable batteries has been noted by
both academia and industry. This has become more prominent with the increasing demand …

Lithium salts for advanced lithium batteries: Li–metal, Li–O 2, and Li–S

R Younesi, GM Veith, P Johansson… - Energy & …, 2015 - pubs.rsc.org
Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial
rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3–4 V cathode …

Electrolyte design for Li-ion batteries under extreme operating conditions

J Xu, J Zhang, TP Pollard, Q Li, S Tan, S Hou, H Wan… - Nature, 2023 - nature.com
The ideal electrolyte for the widely used LiNi0. 8Mn0. 1Co0. 1O2 (NMC811)|| graphite
lithium-ion batteries is expected to have the capability of supporting higher voltages (≥ 4.5 …

Achieving three-dimensional lithium sulfide growth in lithium-sulfur batteries using high-donor-number anions

H Chu, H Noh, YJ Kim, S Yuk, JH Lee, J Lee… - Nature …, 2019 - nature.com
Uncontrolled growth of insulating lithium sulfide leads to passivation of sulfur cathodes,
which limits high sulfur utilization in lithium-sulfur batteries. Sulfur utilization can be …

Chemistry-informed machine learning for polymer electrolyte discovery

G Bradford, J Lopez, J Ruza, MA Stolberg… - ACS Central …, 2023 - ACS Publications
Solid polymer electrolytes (SPEs) have the potential to improve lithium-ion batteries by
enhancing safety and enabling higher energy densities. However, SPEs suffer from …

Controlling electrolyte properties and redox reactions using solvation and implications in battery functions: A Mini‐Review

G Leverick, Y Shao‐Horn - Advanced Energy Materials, 2023 - Wiley Online Library
Electrolytes will play a central role in the development of next‐generation batteries with
increased energy density and cycle life and reduced cost. While molecular designs can …

The plastic-crystalline phase of succinonitrile as a universal matrix for solid-state ionic conductors

PJ Alarco, Y Abu-Lebdeh, A Abouimrane, M Armand - Nature materials, 2004 - nature.com
Solid ionic conductors are actively sought for their potential application in electrochemical
devices, particularly lithium batteries. We have found high ionic conductivity for a large …

Singlet oxygen from cation driven superoxide disproportionation and consequences for aprotic metal–O 2 batteries

E Mourad, YK Petit, R Spezia, A Samojlov… - Energy & …, 2019 - pubs.rsc.org
Aprotic alkali metal–oxygen batteries require reversible formation of metal superoxide or
peroxide on cycling. Severe parasitic reactions cause poor rechargeability, efficiency, and …

Ion transport and structural design of lithium-ion conductive solid polymer electrolytes: a perspective

B Tong, Z Song, H Wu, X Wang, W Feng… - Materials …, 2022 - iopscience.iop.org
Solid polymer electrolytes (SPEs) possess several merits including no leakage, ease in
process, and suppressing lithium dendrites growth. These features are beneficial for …

Anion‐Dependent Redox Chemistry of p‐Type Poly (vinyldimethylphenazine) Cathode Materials

A Duan, Z Wang, X Huang, Y Li - … Chemie International Edition, 2023 - Wiley Online Library
Metal‐free organic electrode materials have attracted vast research attention owing to their
designable structures and tunable electrochemical properties. Although n‐type cathode …