Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Semiconductor nanocrystals for small molecule activation via artificial photosynthesis

XB Li, ZK Xin, SG Xia, XY Gao, CH Tung… - Chemical Society …, 2020 - pubs.rsc.org
Facile activation and conversion of small molecules (eg, H2O, CO2, N2, CH4, and C6H6)
into solar fuels or value-added chemicals under mild conditions is an attractive pathway in …

Atomic‐Level Insight into Optimizing the Hydrogen Evolution Pathway over a Co1‐N4 Single‐Site Photocatalyst

Y Cao, S Chen, Q Luo, H Yan, Y Lin… - Angewandte Chemie …, 2017 - Wiley Online Library
Abstract Knowledge of the photocatalytic H2 evolution mechanism is of great importance for
designing active catalysts toward a sustainable energy supply. An atomic‐level insight …

Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts

KJ Lee, N Elgrishi, B Kandemir… - Nature Reviews Chemistry, 2017 - nature.com
Modern energy challenges have amplified interest in transition metal-based molecular
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …

K-and L-edge X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) determination of differential orbital covalency (DOC) of transition …

ML Baker, MW Mara, JJ Yan, KO Hodgson… - Coordination chemistry …, 2017 - Elsevier
Continual advancements in the development of synchrotron radiation sources have resulted
in X-ray based spectroscopic techniques capable of probing the electronic and structural …

Tracking Mechanistic Pathway of Photocatalytic CO2 Reaction at Ni Sites Using Operando, Time-Resolved Spectroscopy

Y Hu, F Zhan, Q Wang, Y Sun, C Yu… - Journal of the …, 2020 - ACS Publications
Harvesting solar energy for catalytic conversion of CO2 into valuable chemical
fuels/feedstocks is an attractive yet challenging strategy to realize a sustainable carbon …

Precious-Metal-Free CO2 Photoreduction Boosted by Dynamic Coordinative Interaction between Pyridine-Tethered Cu(I) Sensitizers and a Co(II) Catalyst

JW Wang, X Zhang, L Velasco, M Karnahl, Z Li… - JACS Au, 2023 - ACS Publications
Improving the photocatalytic efficiency of a fully noble-metal-free system for CO2 reduction
remains a fundamental challenge, which can be accomplished by facilitating electron …

[HTML][HTML] Hydrogen evolution with hot electrons on a plasmonic-molecular catalyst hybrid system

A Dey, A Mendalz, A Wach, RB Vadell… - Nature …, 2024 - nature.com
Plasmonic systems convert light into electrical charges and heat, mediating catalytic
transformations. However, there is ongoing controversy regarding the involvement of hot …

Heterogeneous Co–N/C electrocatalysts with controlled cobalt site densities for the hydrogen evolution reaction: structure–activity correlations and kinetic insights

YJ Sa, SO Park, GY Jung, TJ Shin, HY Jeong… - ACS …, 2018 - ACS Publications
The development of active and stable non-precious-metal electrocatalysts for energy
conversion reactions involving hydrogen and oxygen has been of pivotal importance for …

Self-assembled framework enhances electronic communication of ultrasmall-sized nanoparticles for exceptional solar hydrogen evolution

XB Li, YJ Gao, Y Wang, F Zhan, XY Zhang… - Journal of the …, 2017 - ACS Publications
Colloidal quantum dots (QDs) have demonstrated great promise in artificial photosynthesis.
However, the ultrasmall size hinders its controllable and effective interaction with …