Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …
challenging and important chemical transformations. Notwithstanding the barriers …
Dinitrogen coordination chemistry: on the biomimetic borderlands
BA MacKay, MD Fryzuk - Chemical reviews, 2004 - ACS Publications
Biological nitrogen fixation by the nitrogenase enzymes has long been a touchstone for
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …
Preparation and molecular and electronic structures of iron (0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation
Reduction of the five-coordinate iron (II) dihalide complexes (iPrPDI) FeX2 (iPrPDI=((2, 6-
CHMe2) 2C6H3N CMe) 2C5H3N; X= Cl, Br) with sodium amalgam under 1 atm of dinitrogen …
CHMe2) 2C6H3N CMe) 2C5H3N; X= Cl, Br) with sodium amalgam under 1 atm of dinitrogen …
Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide
JH Docherty, J Peng, AP Dominey, SP Thomas - Nature Chemistry, 2017 - nature.com
First-row, earth-abundant metals offer an inexpensive and sustainable alternative to
precious-metal catalysts. As such, iron and cobalt catalysts have garnered interest as …
precious-metal catalysts. As such, iron and cobalt catalysts have garnered interest as …
Iron–dinitrogen coordination chemistry: dinitrogen activation and reactivity
JL Crossland, DR Tyler - Coordination Chemistry Reviews, 2010 - Elsevier
Understanding the coordination of dinitrogen to iron is important for understanding
biological nitrogen fixation as well as for designing synthetic systems that are capable of …
biological nitrogen fixation as well as for designing synthetic systems that are capable of …
1, 4-Functionalization of 1, 3-dienes with low-valent iron catalysts
E McNeill, T Ritter - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Iron-catalyzed or-mediated transformations of organic substrates have been
important throughout the development of organic chemistry due to iron's abundance, low …
important throughout the development of organic chemistry due to iron's abundance, low …
[图书][B] Transition Metal-Dinitrogen Complexes: Preparation and Reactivity
Y Nishibayashi - 2019 - books.google.com
A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen
complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This …
complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This …
Recent advances in catalytic silylation of dinitrogen using transition metal complexes
Y Tanabe, Y Nishibayashi - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract Development of catalytic silylation of dinitrogen into silylamines using transition
metal complexes under ambient reaction conditions precedes the development of catalytic …
metal complexes under ambient reaction conditions precedes the development of catalytic …
Low-valent α-diimine iron complexes for catalytic olefin hydrogenation
A family of low-valent α-diimine iron complexes has been synthesized and their utility in
catalytic olefin hydrogenation reactions evaluated. Reduction of the ferrous dichloride …
catalytic olefin hydrogenation reactions evaluated. Reduction of the ferrous dichloride …
Boron Insertion into the N≡ N Bond of a Tungsten Dinitrogen Complex
LC Haufe, L Endres, M Arrowsmith… - Journal of the …, 2023 - ACS Publications
The 1, 3-addition of 1, 2-diaryl-1, 2-dibromodiboranes (B2Br2Ar2) to trans-[W (N2) 2 (dppe)
2](dppe= κ2-(Ph2PCH2) 2), which is accompanied by a Br–Ar substituent exchange …
2](dppe= κ2-(Ph2PCH2) 2), which is accompanied by a Br–Ar substituent exchange …