Abstract Discovered in 2005, cyclic (alkyl)(amino) carbenes (CAACs) are among the most
nucleophilic (σ donating) and also electrophilic (π‐accepting) stable carbenes known to …

Ein Kennzeichen der seit 2005 bekannten cyclischen Alkylaminocarbene (CAACs) ist ihre
ausgeprägte Nucleophilie (σ‐Donor) und zugleich Elektrophile (π‐Akzeptor). Diese …

Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

A versatile methodology, involving readily available starting materials, allows for the
synthesis of stable hemilabile bidentate cyclic (alkyl)(amino) carbenes (CAACs) featuring …

bis [2, 6‐bis [di (4‐tert‐butylphenyl) methyl]‐4‐methylphenyl] imidazol‐2‐ylidene) CuOPh
[(IPr**) CuOPh] reacts with poly (methylhydrosiloxane) as the hydride donor to afford the …

A series of 16 novel spirooxindole analogs 8a–p were designed and constructed via cost‐
effective single‐step multicomponent [3+ 2] cycloaddition reaction of azomethine ylide (AY) …

Reaction of triazolium precursors [MIC (CH2) n‐H+] I−(n= 1–3) with potassium
hexamethyldisilazane (KHMDS) and AuCl (SMe2) generates the gold (I) complexes of the …

This review continues consideration of the regioselectivity problem in the catalyzed
hydrofunctionalization of unsaturated organic compounds and addresses hydroamination of …

The facile preparation of a C 4-symmteric tetratriazolium salt and its subsequent metalation
to generate a series of tetranuclear mesoionic carbene gold (I) complexes is presented. The …

A copper-catalyzed stereoselective phosphono-hydrazonation of terminal alkynes with alkyl
carbazates and diarylphosphine oxides is described. This methodology provides facile …