Synthesis of isocoumarins and α-pyrones via electrophilic cyclization

T Yao, RC Larock - The Journal of organic chemistry, 2003 - ACS Publications
A variety of substituted isocoumarins and α-pyrones are readily prepared in excellent yields
under very mild reaction conditions by the reaction of o-(1-alkynyl) benzoates and (Z)-2 …

Synthesis of isoxazoles via electrophilic cyclization

JP Waldo, RC Larock - Organic letters, 2005 - ACS Publications
Synthesis of Isoxazoles via Electrophilic Cyclization | Organic Letters ACS ACS Publications
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Regio-and stereoselective synthesis of isoindolin-1-ones via electrophilic cyclization

T Yao, RC Larock - The Journal of organic chemistry, 2005 - ACS Publications
A variety of substituted isoindolin-1-ones are readily prepared in good to excellent yields
under very mild reaction conditions by the reaction of o-(1-alkynyl) benzamides with ICl, I2 …

Catalyst-free synthesis of borylated lactones from esters via electrophilic oxyboration

DJ Faizi, A Issaian, AJ Davis… - Journal of the American …, 2016 - ACS Publications
A catalyst-free oxyboration reaction of alkynes is developed. The resulting borylated
isocoumarins and 2-pyrones are isolated as boronic acids, pinacolboronate esters, or …

The synthesis of highly substituted isoxazoles by electrophilic cyclization: an efficient synthesis of valdecoxib

JP Waldo, RC Larock - The Journal of organic chemistry, 2007 - ACS Publications
A large number of functionally substituted 2-alkyn-1-one O-methyl oximes have been
cyclized under mild reaction conditions in the presence of ICl to give the corresponding 4 …

Synthesis of 3-Iodoindoles by the Pd/Cu-Catalyzed Coupling of N,N-Dialkyl-2-iodoanilines and Terminal Acetylenes, Followed by Electrophilic Cyclization

D Yue, T Yao, RC Larock - The Journal of organic chemistry, 2006 - ACS Publications
3-Iodoindoles have been prepared in excellent yields by coupling terminal acetylenes with
N, N-dialkyl-o-iodoanilines in the presence of a Pd/Cu catalyst, followed by an electrophilic …

Synthesis of polycyclic aromatics and heteroaromatics via electrophilic cyclization

T Yao, MA Campo, RC Larock - The Journal of Organic Chemistry, 2005 - ACS Publications
A variety of substituted polycyclic aromatics are readily prepared in good to excellent yields
under very mild reaction conditions by the reaction of 2-(1-alkynyl) biphenyls with ICl, I2 …

Diversity-oriented synthesis of 3-iodochromones and heteroatom analogues via ICl-induced cyclization

C Zhou, AV Dubrovsky, RC Larock - The Journal of Organic …, 2006 - ACS Publications
The ICl-induced cyclization of heteroatom-substituted alkynones provides a simple, highly
efficient approach to various 3-iodochromones and analogues. This process is run under …

Synthesis of Isocoumarins via Pd/C-Mediated Reactions of o-Iodobenzoic Acid with Terminal Alkynes

V Subramanian, VR Batchu, D Barange… - The Journal of Organic …, 2005 - ACS Publications
The coupling reaction of o-iodobenzoic acid with terminal alkynes by using a catalyst system
of 10% Pd/C− Et3N− CuI− PPh3 has been studied in a variety of solvents. 3-Substituted …

Electrophile-driven regioselective synthesis of functionalized quinolines

S Ali, HT Zhu, XF Xia, KG Ji, YF Yang, XR Song… - Organic …, 2011 - ACS Publications
Highly substituted 3-iodoquinolines bearing different alkyl and aryl moieties can be
synthesized in moderate to excellent yields (up to 99%) by 6-endo-dig iodocyclization of 2 …