Cage compounds offer unique binding pockets similar to enzyme-binding sites, which can
be customized in terms of size, shape, and functional groups to point toward the cavity and …

Chiroptical responses have been an essential tool over the last decades for chemical
structural elucidation due to their exceptional sensitivity to geometry and intermolecular …

The development of synthetic host–guest chemistry to investigate and quantify weak, non-
covalent interactions has been key to unraveling the complexity of molecular recognition in …

Abstract Four enantiopure 1, 3‐diethynylallenes (DEAs) with OH termini were attached to the
rim of a resorcin [4] arene cavitand. The system undergoes conformational switching …

Several theoretical studies have proposed strategies to generate helical molecular orbitals
(Hel‐MOs) in [n] cumulenes and oligoynes. While chiral even‐[n] cumulenes feature Hel …

Enantiopure alleno-acetylenic cage (AAC) receptors with a resorcin [4] arene scaffold, from
which four homochiral alleno-acetylenes converge to shape a cavity closed by a four-fold …

Chirality, a characteristic tool of molecular recognition in nature, is often a complement of
redox active systems. Scientists, in their eagerness to mimic such sophistication, have …

Dynamic alkyne metathesis has successfully been employed toward the synthesis of shape-
persistent macrocycles and covalent organic polyhedrons (COPs). In this contribution, we …

State‐of‐the‐art chiroptical spectroscopies are valuable tools for structural elucidation.
However, the potential of these spectroscopies for everyday applications has not been …

Chiroptical methods have been proven to be superior compared to their achiral counterparts
for the structural elucidation of many compounds. To expand the use of chiroptical systems …