Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …

Chiral Hydride Cu18 Clusters Transform to Superatomic Cu15Ag4 Clusters: Circularly Polarized Luminescence Lighting

MM Zhang, KK Gao, XY Dong, Y Si, T Jia… - Journal of the …, 2023 - ACS Publications
The manipulation of metal cluster enantiomers and their reconstruction remain challenging.
Here, for the first time, we report an enantiomeric pair of hydride copper clusters [Cu18H …

Atomic-level doping of metal clusters

A Ghosh, OF Mohammed, OM Bakr - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Atomically precise noble metal (mainly silver and gold) nanoclusters are an
emerging category of promising functional materials for future applications in energy …

Boosting CO2 Electrochemical Reduction with Atomically Precise Surface Modification on Gold Nanoclusters

S Li, AV Nagarajan, DR Alfonso, M Sun… - Angewandte Chemie …, 2021 - Wiley Online Library
Thiolate‐protected gold nanoclusters (NCs) are promising catalytic materials for the
electrochemical CO2 reduction reaction (CO2RR). In this work an atomic level modification …

Engineering functional metal materials at the atomic level

Q Yao, X Yuan, T Chen, DT Leong, J Xie - Advanced Materials, 2018 - Wiley Online Library
With continuous research efforts devoted into synthesis and characterization chemistry of
functional nanomaterials in the past decades, the development of metal materials is …

Chirality and surface bonding correlation in atomically precise metal nanoclusters

Y Li, T Higaki, X Du, R Jin - Advanced Materials, 2020 - Wiley Online Library
Chirality is ubiquitous in nature and occurs at all length scales. The development of
applications for chiral nanostructures is rising rapidly. With the recent achievements of …