Harnessing metal‐free photoinduced reversible‐deactivation radical polymerization (photo‐
RDRP) in organic and aqueous phases, we report a synthetic approach to enzyme …

Deterministic methods for tuning polymer dispersity are rare, especially for nonradical
polymerizations. Reported here is the first example of photomodulating dispersity in …

Light‐mediated coupling of acylsilanes with indoles is reported. This photo click reaction
occurs under mild conditions (415 nm) mostly in quantitative yield and provides stable …

A novel broad‐wavelength‐absorbing photoinitiator based on phenacyl phenothiazinium
hexafluroantimonate (P‐PTh) possessing both phenacyl and phenothiazine chromophoric …

Polymerizations of perfluorinated vinyl ethers (PFVEs) provide an important category of
fluoropolymers that have received considerable interests in applications. In this work, we …

Photo-controlled living polymerization has received great attention in recent years. However,
despite the great success therein, the report on photo-controlled living cationic …

Abstract Ultra‐high‐molecular‐weight (UHMW) polymers display outstanding properties and
hold potential for wide applications. However, their precise synthesis remains challenging …

The synthesis of high‐molecular‐weight poly (vinyl ethers) under mild conditions is a
significant challenge, since cationic polymerization reactions are highly sensitive to chain …

Photo‐controlled polymerizations are attractive to tailor macromolecules of complex
compositions with spatiotemporal regulation. In this work, with a convenient synthesis for …

Gaining temporal control over chain growth is a key challenge in the enhancement of
controlled living polymerizations. Though research on photocontrolled polymerizations is …