The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics

Y Zhang, SH Pun, Q Miao - Chemical Reviews, 2022 - ACS Publications
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …

Nanographenes and graphene nanoribbons as multitalents of present and future materials science

Y Gu, Z Qiu, K Müllen - Journal of the American Chemical …, 2022 - ACS Publications
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …

Helical bilayer nanographenes: impact of the helicene length on the structural, electrochemical, photophysical, and chiroptical properties

P Izquierdo-García, JM Fernández-García… - Journal of the …, 2023 - ACS Publications
Helical bilayer nanographenes (HBNGs) are chiral π-extended aromatic compounds
consisting of two π–π stacked hexabenzocoronenes (HBCs) joined by a helicene, thus …

Polycyclic aromatic hydrocarbon-based organic semiconductors: ring-closing synthesis and optoelectronic properties

Q Li, Y Zhang, Z Xie, Y Zhen, W Hu… - Journal of Materials …, 2022 - pubs.rsc.org
Polycyclic aromatic hydrocarbons (PAHs) as a typical class of organic semiconductors
demonstrate unique optical, electrical, magnetic and other interesting properties due to their …

Synthetic chiral molecular nanographenes: the key figure of the racemization barrier

JM Fernández-García, P Izquierdo-García… - Chemical …, 2022 - pubs.rsc.org
Chirality is one of the most intriguing concepts of chemistry, involving living systems and,
more recently, materials science. In particular, the bottom-up synthesis of molecular …

Synthesis of a Dicyclohepta[a,g]heptalene‐Containing Polycyclic Conjugated Hydrocarbon and the Impact of Non‐Alternant Topologies

J Wang, FG Gámez, J Marín‐Beloqui… - Angewandte …, 2023 - Wiley Online Library
Incorporating non‐hexagonal rings into polycyclic conjugated hydrocarbons (PCHs) can
significantly affect their electronic and optoelectronic properties and chemical reactivities …

Polycyclic aromatic hydrocarbons in the graphene era

XY Wang, X Yao, K Müllen - Science China Chemistry, 2019 - Springer
Polycyclic aromatic hydrocarbons (PAHs) have been the subject of interdisciplinary research
in the fields of chemistry, physics, materials science, and biology. Notably, PAHs have drawn …

Chirality amplified: long, discrete helicene nanoribbons

X Xiao, SK Pedersen, D Aranda, J Yang… - Journal of the …, 2020 - ACS Publications
Here we report the synthesis of two polyhelicene frameworks consisting, from end-to-end, of
18 and 24 fused benzene rings. The latter exhibits the largest electronic circular dichroism in …

Synthesis and chiral resolution of twisted carbon nanobelts

W Fan, T Matsuno, Y Han, X Wang… - Journal of the …, 2021 - ACS Publications
Twisted carbon nanobelts could display persistent chirality, which is desirable for material
applications, but their synthesis is very challenging. Herein, we report the successful …

Azulene‐Embedded [n]Helicenes (n=5, 6 and 7)

C Duan, J Zhang, J Xiang, X Yang… - Angewandte Chemie …, 2022 - Wiley Online Library
Azulene is a non‐benzenoid aromatic building block with unique chemical structure and
physicochemical properties. By using the “bottom‐up” synthetic strategy, we synthesized …