[PDF][PDF] Advances and challenges in the synthesis of pyrrole systems of a limited access

DA Shabalin, EY Schmidt, BA Trofimov - Targets in Heterocyclic Systems, 2017 - soc.chim.it
This chapter focuses on the advances and challenges in the synthesis of selected hardly
accessible pyrrole systems. The review is divided into three main sections namely the …

Recent advances in the synthesis of heterocycles from oximes (2014-2017)

E Abele, R Abele - Current Organic Chemistry, 2018 - ingentaconnect.com
This review illustrates that oximes and their derivatives are valuable materials for the
preparation of different classes of heterocyclic compounds. The main group of reactions …

3H-Pyrroles as a platform for the catalyst-free construction of dihydropyrrolo [2, 1-b] oxazoles:[4+ 2]-cycloaddition vs [2+ 3]-annulation with 1-cyano-3-hydroxyalkynes

LA Oparina, DA Shabalin, NA Kolyvanov, U Igor'A… - Tetrahedron …, 2019 - Elsevier
Abstract Non-aromatic pyrrole isomers, 3, 3-dialkyl-2-aryl-3H-pyrroles, were reacted with 1-
cyano-3-hydroxyalkynes under mild, catalyst-free conditions (20–60° C) to regio-and …

Superbase‐catalyzed domino 3H‐pyrroles synthesis from ketoximes and acetylene: DFT study vs experiment

AV Kuzmin, DA Shabalin - Journal of Physical Organic …, 2018 - Wiley Online Library
Elimination of vinyl alcohol from 5‐vinyloxypyrrolines in the presence of superbases (final
step of domino 3 H‐pyrroles synthesis from ketoximes and acetylene) is studied …

Synthesis of 3H-pyrroles (microreview)

MY Belikov, OV Ershov - Chemistry of Heterocyclic Compounds, 2016 - Springer
Synthesis of 3H-pyrroles (microreview) Page 1 279 Chemistry of Heterocyclic Compounds
2016, 52(5), 279–281 Synthesis of 3H-pyrroles (microreview) Mikhail Yu. Belikov1*, Oleg V …

Noncatalytic Annulation of 4-Hydroxy-4-methylpent-2-ynenitrile to 3,3-Dimethyl-2-phenyl-3H-pyrrole. Stereoselective Synthesis of (Z)-2-(2,2,7,7-Tetramethyl-7a-phenyl-7,7a …

LA Oparina, DA Shabalin, NA Kolyvanov… - Russian Journal of …, 2018 - Springer
Dimethyl-2-phenyl-3 H-pyrrole reacted with 4-hydroxy-4-methylpent-2-ynenitrile under mild
conditions (20–25° C, 5 days) to give (Z)-2-(2, 2, 7, 7-tetramethyl-7a-phenyl-7, 7a …

Secondary Alkyl Ketoximes in the Trofimov Reaction: From Minor Products to 21st Century Reagents

DA Shabalin - Russian Journal of Organic Chemistry, 2023 - Springer
The review summarizes the results and prospects of studying the reactions of acetylene with
secondary alkyl ketoximes containing only one C–H bond at the α-position with respect to …

First Example of the Aza-Favorskii Reaction. Ethynylation of C=N Bond in the Superbasic System t-BuOK–DMSO

IA Bidusenko, EY Schmidt, BA Trofimov - Russian Journal of Organic …, 2018 - Springer
First Example of the Aza-Favorskii Reaction. Ethynylation of C=N Bond in the Superbasic System
t-BuOK–DMSO Page 1 1422 First Example of the Aza-Favorskii Reaction. Ethynylation of C=N …

Synthesis of 3, 7, 9-triazatricyclo [6.2. 1.0] undeca-2, 4-dienes by reaction of 2-oxa-7-azaspiro [4.4] nona-3, 6, 8-trienes with sodium hydroxide.

M Belikov, I Belikova, O Ershov… - Russian Journal of …, 2016 - search.ebscohost.com
The article presents a study which focuses on the use of the reaction of 2-Oxa-7-azaspiro
[4.4] nona-3, 6, 8-trienes with sodium hydroxide in the synthesis of 3, 7, 9-triazatricyclo [6.2 …

sec-Alkylketoximes in the Trofimov reaction: from minor products to reagents of the XXI century

DA Shabalin - Žurnal organičeskoj himii, 2023 - journals.rcsi.science
This review summarizes the results and perspectives of studies of the reaction between sec-
alkylketoximes having only one CH bond at the α-position to the oxime function and …