Different Photodissociation Mechanisms in Fe(CO)5 and Cr(CO)6 Evidenced with Femtosecond Valence Photoelectron Spectroscopy and Excited-State Molecular …
Measured and calculated time-resolved photoelectron spectra and excited-state molecular
dynamics simulations of photoexcited gas-phase molecules Fe (CO) 5 and Cr (CO) 6 are …
dynamics simulations of photoexcited gas-phase molecules Fe (CO) 5 and Cr (CO) 6 are …
Ultrafast Production of NiCO and Ni Following 197 nm Photodissociation of Nickel Tetracarbonyl
NC Cole-Filipiak, J Troß, P Schrader… - ACS Physical …, 2024 - ACS Publications
Herein, we report on the ultrafast photodissociation of nickel tetracarbonyl─ a prototypical
metal–ligand model system─ at 197 nm. Using mid-infrared transient absorption …
metal–ligand model system─ at 197 nm. Using mid-infrared transient absorption …
Real-space Observation of a Transition Metal Complex Dissociation and Energy Redistribution
Mechanistic insights into photodissociation dynamics of transition metal carbonyls, like Fe
(CO) $ _5 $, are fundamental for understanding active catalytic intermediates. Although …
(CO) $ _5 $, are fundamental for understanding active catalytic intermediates. Although …