Fundamentals of TiO2 Photocatalysis: Concepts, Mechanisms, and Challenges

Q Guo, C Zhou, Z Ma, X Yang - Advanced Materials, 2019 - Wiley Online Library
Photocatalysis has been widely applied in various areas, such as solar cells, water splitting,
and pollutant degradation. Therefore, the photochemical mechanisms and basic principles …

A surface science perspective on TiO2 photocatalysis

MA Henderson - Surface Science Reports, 2011 - Elsevier
The field of surface science provides a unique approach to understanding bulk, surface and
interfacial phenomena occurring during TiO 2 photocatalysis. This review highlights, from a …

Many-body methods for surface chemistry come of age: Achieving consensus with experiments

BX Shi, A Zen, V Kapil, PR Nagy… - Journal of the …, 2023 - ACS Publications
The adsorption energy of a molecule onto the surface of a material underpins a wide array of
applications, spanning heterogeneous catalysis, gas storage, and many more. It is the key …

Titanium dioxide photocatalysis in atmospheric chemistry

H Chen, CE Nanayakkara, VH Grassian - Chemical reviews, 2012 - ACS Publications
1. INTRODUCTION Titanium dioxide (TiO2) is a relatively inexpensive, nontoxic, and easy to
handle material, which is of great interest, as evidenced by the wide number of applications …

IR spectroscopic investigations of chemical and photochemical reactions on metal oxides: bridging the materials gap

Y Wang, C Wöll - Chemical Society Reviews, 2017 - pubs.rsc.org
In this review, we highlight recent progress (2008–2016) in infrared reflection absorption
spectroscopy (IRRAS) studies on oxide powders achieved by using different types of metal …

Structure of Clean and Adsorbate-Covered Single-Crystal Rutile TiO2 Surfaces

CL Pang, R Lindsay, G Thornton - Chemical reviews, 2013 - ACS Publications
TiO 2 is exploited in a number of applications, including solar power, catalysis, gas sensing,
and corrosion protection, where surface properties are central to operation. This commercial …

Site Sensitivity of Interfacial Charge Transfer and Photocatalytic Efficiency in Photocatalysis: Methanol Oxidation on Anatase TiO2 Nanocrystals

C Fu, F Li, J Zhang, D Li, K Qian, Y Liu… - Angewandte Chemie …, 2021 - Wiley Online Library
Photocatalytic oxidation of methanol on various anatase TiO2 nanocrystals was studied by
in situ and time‐resolved characterizations and DFT calculations. Surface site and resulting …

Molecular-Level Insights into Photocatalysis from Scanning Probe Microscopy Studies on TiO2(110)

MA Henderson, I Lyubinetsky - Chemical Reviews, 2013 - ACS Publications
The field of heterogeneous photocatalysis has grown considerably in the decades since
Fujishima and Honda's ground-breaking publications on photoelectrochemistry on TiO2. 1 …

Electron traps and their effect on the surface chemistry of TiO2(110)

AC Papageorgiou, NS Beglitis… - Proceedings of the …, 2010 - National Acad Sciences
Oxygen vacancies on metal oxide surfaces have long been thought to play a key role in the
surface chemistry. Such processes have been directly visualized in the case of the model …

Thermally-driven processes on rutile TiO2 (1 1 0)-(1× 1): A direct view at the atomic scale

Z Dohnálek, I Lyubinetsky, R Rousseau - Progress in Surface Science, 2010 - Elsevier
The technological importance of TiO2 has led to a broad effort aimed at understanding the
elementary steps that underlie catalytic and photocatalytic reactions. The most stable …