Roaming radicals

JM Bowman, BC Shepler - Annual review of physical chemistry, 2011 - annualreviews.org
Roaming is a recently verified unusual pathway to molecular products from unimolecular
dissociation of an energized molecule. Here we present the evidence for this pathway for …

Roaming Reactions and Dynamics in the van der Waals Region

AG Suits - Annual Review of Physical Chemistry, 2020 - annualreviews.org
Roaming reactions were first clearly identified in photodissociation of formaldehyde 15 years
ago, and roaming dynamics are now recognized as a universal aspect of chemical reactivity …

A Hierarchical and Comparative Kinetic Modeling Study of C1 − C2 Hydrocarbon and Oxygenated Fuels

WK Metcalfe, SM Burke, SS Ahmed… - International Journal of …, 2013 - Wiley Online Library
ABSTRACT A detailed chemical kinetic mechanism has been developed to describe the
oxidation of small hydrocarbon and oxygenated hydrocarbon species. The reactivity of these …

Rate constants for the thermal decomposition of ethanol and its bimolecular reactions with OH and D: reflected shock tube and theoretical studies

R Sivaramakrishnan, MC Su, JV Michael… - The Journal of …, 2010 - ACS Publications
The thermal decomposition of ethanol and its reactions with OH and D have been studied
with both shock tube experiments and ab initio transition state theory-based master equation …

Plasma-Assisted Dry Reforming of CH4: How Small Amounts of O2 Addition Can Drastically Enhance the Oxygenate Production─Experiments and Insights from …

S Li, J Sun, Y Gorbanev, K van't Veer… - ACS Sustainable …, 2023 - ACS Publications
Plasma-based dry reforming of methane (DRM) into high-value-added oxygenates is an
appealing approach to enable otherwise thermodynamically unfavorable chemical reactions …

Infrared radiation and planetary temperature

RT Pierrehumbert - Physics Today, 2011 - pubs.aip.org
Infrared radiation and planetary temperature | Physics Today | AIP Publishing Skip to Main
Content Search Dropdown Menu header search search input Search input auto suggest filter …

A chemical kinetics network for lightning and life in planetary atmospheres

PB Rimmer, C Helling - The Astrophysical Journal Supplement …, 2016 - iopscience.iop.org
There are many open questions about prebiotic chemistry in both planetary and
exoplanetary environments. The increasing number of known exoplanets and other ultra …

Substitution reactions in the pyrolysis of acetone revealed through a modeling, experiment, theory paradigm

DP Zaleski, R Sivaramakrishnan… - Journal of the …, 2021 - ACS Publications
The development of high-fidelity mechanisms for chemically reactive systems is a
challenging process that requires the compilation of rate descriptions for a large and …

Development of an ethanol combustion mechanism based on a hierarchical optimization approach

C Olm, T Varga, É Valkó, S Hartl… - … Journal of Chemical …, 2016 - Wiley Online Library
ABSTRACT A detailed reaction mechanism for ethanol combustion was developed for
describing ignition, flame propagation, and species concentration profiles with high …

Theories and simulations of roaming

JM Bowman, PL Houston - Chemical Society Reviews, 2017 - pubs.rsc.org
The phenomenon of roaming in chemical reactions has now become both commonly
observed in experiment and extensively supported by theory and simulations. Roaming …