The sabatier principle in electrocatalysis: Basics, limitations, and extensions

H Ooka, J Huang, KS Exner - Frontiers in Energy Research, 2021 - frontiersin.org
The Sabatier principle, which states that the binding energy between the catalyst and the
reactant should be neither too strong nor too weak, has been widely used as the key …

Self-adaptive amorphous CoOxCly electrocatalyst for sustainable chlorine evolution in acidic brine

M Xiao, Q Wu, R Ku, L Zhou, C Long, J Liang… - Nature …, 2023 - nature.com
Electrochemical chlorine evolution reaction is of central importance in the chlor-alkali
industry, but the chlorine evolution anode is largely limited by water oxidation side reaction …

Atomic Pt‐N4 Sites in Porous N‐Doped Nanocarbons for Enhanced On‐Site Chlorination Coupled with H2 Evolution in Acidic Water

L Quan, X Chen, J Liu, S Fan, BY Xia… - Advanced Functional …, 2023 - Wiley Online Library
Acidic water electrolysis (AWE) has the potential to revolutionize green H2 generation with
flexible partial load range, high gas purity, and rapid system response. However, the …

[HTML][HTML] Circumventing the OCl versus OOH scaling relation in the chlorine evolution reaction: Beyond dimensionally stable anodes

KS Exner, T Lim, SH Joo - Current Opinion in Electrochemistry, 2022 - Elsevier
The development of selective electrocatalysts for the chlorine evolution reaction (CER) is
majorly restrained by a scaling relation between the OCl and OOH adsorbates, rendering …

Atomically dispersed Pt–N4 sites as efficient and selective electrocatalysts for the chlorine evolution reaction

T Lim, GY Jung, JH Kim, SO Park, J Park… - Nature …, 2020 - nature.com
Chlorine evolution reaction (CER) is a critical anode reaction in chlor-alkali electrolysis.
Although precious metal-based mixed metal oxides (MMOs) have been widely used as CER …

Selective anodes for seawater splitting via functionalization of manganese oxides by a plasma-assisted process

L Bigiani, D Barreca, A Gasparotto, T Andreu… - Applied Catalysis B …, 2021 - Elsevier
The electrolysis of seawater, a significantly more abundant natural reservoir than freshwater,
stands as a promising alternative for sustainable hydrogen production, provided that the …

Selective electrosynthesis of chlorine disinfectants from seawater

S Zhao, H Li, J Dai, Y Jiang, G Zhan, M Liao… - Nature …, 2024 - nature.com
As one of the most widely used disinfectants, active chlorine is synthesized predominantly
through electrolysis of saturated sodium chloride solutions, an industrial process known as …

General efficacy of atomically dispersed Pt catalysts for the chlorine evolution reaction: potential-dependent switching of the kinetics and mechanism

T Lim, JH Kim, J Kim, DS Baek, TJ Shin, HY Jeong… - ACS …, 2021 - ACS Publications
The electrochemical chlorine evolution reaction (CER) is a key anodic reaction in the chlor-
alkali process for Cl2 production, on-site generation of ClO–, and Cl2-mediated …

Facing Seawater Splitting Challenges by Regeneration with NiMoFe Bifunctional Electrocatalyst for Hydrogen and Oxygen Evolution

C Ros, S Murcia‐López, X Garcia, M Rosado… - …, 2021 - Wiley Online Library
Hydrogen, produced by water splitting, has been proposed as one of the main green energy
vectors of the future if produced from renewable energy sources. However, to substitute …

Construction of the multi-layer TiO2-NTs/Sb-SnO2/PbO2 electrode for the highly efficient and selective oxidation of ammonia in aqueous solution: Characterization …

Z Zhang, J Liu, H Ai, A Chen, L Xu, L Labiadh… - Journal of …, 2023 - Elsevier
Electrochemical oxidation is a promising technology to convert ammonia nitrogen to
environmental-friendly gaseous nitrogen, but the high cost of the precious metal as an …