Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals
P Loxq, E Manoury, R Poli, E Deydier… - Coordination Chemistry …, 2016 - Elsevier
Axially chiral biaryl structures are unique systems encountered in various synthetic
compounds such as BINAP and BINOL, polymers, but also in natural products presenting a …
compounds such as BINAP and BINOL, polymers, but also in natural products presenting a …
Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands
MA Kinzhalov, EV Grachova… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as
powerful emitters for prospective use in OLEDs and other electroluminescent technologies …
powerful emitters for prospective use in OLEDs and other electroluminescent technologies …
Complex N-heterocycle synthesis via iron-catalyzed, direct C–H bond amination
ET Hennessy, TA Betley - Science, 2013 - science.org
The manipulation of traditionally unreactive functional groups is of paramount importance in
modern chemical synthesis. We have developed an iron-dipyrrinato catalyst that leverages …
modern chemical synthesis. We have developed an iron-dipyrrinato catalyst that leverages …
Enantioselective alkynylbenzaldehyde cyclizations catalyzed by chiral gold (I) acyclic diaminocarbene complexes containing weak Au–arene interactions
S Handa, LGM Slaughter - Angewandte Chemie International Edition, 2012 - infona.pl
Hold me close: Highly enantioselective catalysis of tandem acetalization/cycloisomerization
reactions of o‐alkynylbenzaldehydes has been achieved using gold complexes of chiral …
reactions of o‐alkynylbenzaldehydes has been achieved using gold complexes of chiral …
N‐Heterocyclic Carbene Iron(III) Porphyrin‐Catalyzed Intramolecular C(sp3)–H Amination of Alkyl Azides
KP Shing, Y Liu, B Cao, XY Chang… - Angewandte Chemie …, 2018 - Wiley Online Library
Metal‐catalyzed intramolecular C− H amination of alkyl azides constitutes an appealing
approach to alicyclic amines; challenges remain in broadening substrate scope, enhancing …
approach to alicyclic amines; challenges remain in broadening substrate scope, enhancing …
Acyclic diaminocarbenes (ADCs) as a promising alternative to N-heterocyclic carbenes (NHCs) in transition metal catalyzed organic transformations
Starting from the first reported application of complexes bearing acyclic diaminocarbene
(ADC) ligands as catalysts ca. 5 years ago, these compounds have been successfully …
(ADC) ligands as catalysts ca. 5 years ago, these compounds have been successfully …
Acyclic aminocarbenes in catalysis
LGM Slaughter - ACS Catalysis, 2012 - ACS Publications
Acyclic aminocarbenes have received much less attention as ancillary ligands in
homogeneous catalysis compared with their cyclic relatives (ie, N-heterocyclic carbenes …
homogeneous catalysis compared with their cyclic relatives (ie, N-heterocyclic carbenes …
Synthesis and catalytic applications of palladium N-heterocyclic carbene complexes as efficient pre-catalysts for Suzuki–Miyaura and Sonogashira coupling reactions
L Boubakri, S Yasar, V Dorcet, T Roisnel… - New Journal of …, 2017 - pubs.rsc.org
A new palladium complex series with N-heterocyclic carbene (NHC), pyridine and
phosphine ligands, PdCl2 (L) NHC (2a–c)(L= NHC), PdCl2 (L1) NHC (3a–c)(L1= pyridine) …
phosphine ligands, PdCl2 (L) NHC (2a–c)(L= NHC), PdCl2 (L1) NHC (3a–c)(L1= pyridine) …
Synthesis and contemporary applications of platinum group metals complexes with acyclic diaminocarbene ligands
MA Kinzhalov, KV Luzyanin - Russian Journal of Inorganic Chemistry, 2022 - Springer
Complexes of platinum group metals with acyclic diaminocarbene ligands have found
application as transition metal catalysts, photoluminescent materials, chemosensors, and …
application as transition metal catalysts, photoluminescent materials, chemosensors, and …
From isonitriles to carbenes: Synthesis of new NAC− and NHC− palladium (II) compounds and their catalytic activity
ASK Hashmi, C Lothschütz, C Böhling… - …, 2011 - ACS Publications
A series of NAC− and their structurally related NHC− palladium (II) isonitrile complexes,
including examples of dinuclear complexes, were prepared. In a second series, NHC …
including examples of dinuclear complexes, were prepared. In a second series, NHC …