Difunctionalization of alkenes involving metal migration

Y Li, D Wu, HG Cheng, G Yin - … Chemie International Edition, 2020 - Wiley Online Library
The direct difunctionalization of alkenes, a cheap and abundant feedstock, represents one of
the most attractive strategies for increasing molecular complexity in synthetic organic …

Ligand-promoted palladium-catalyzed aerobic oxidation reactions

D Wang, AB Weinstein, PB White, SS Stahl - Chemical reviews, 2017 - ACS Publications
Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

Nickel-catalyzed dicarbofunctionalization of alkenes

X Qi, T Diao - ACS catalysis, 2020 - ACS Publications
1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

Transition metal‐catalyzed dicarbofunctionalization of unactivated olefins

RK Dhungana, S Kc, P Basnet, R Giri - The Chemical Record, 2018 - Wiley Online Library
Transition metal (TM)‐catalyzed difunctionalization of unactivated olefins with two carbon‐
based entities is a powerful method to construct complex molecular architectures rapidly …

Photochemical C–H activation enables nickel-catalyzed olefin dicarbofunctionalization

MW Campbell, M Yuan, VC Polites… - Journal of the …, 2021 - ACS Publications
Alkenes, ethers, and alcohols account for a significant percentage of bulk reagents available
to the chemistry community. The petrochemical, pharmaceutical, and agrochemical …

Radical-triggered translocation of C–C double bond and functional group

S Wang, X Luo, Y Wang, Z Liu, Y Yu, X Wang, D Ren… - Nature Chemistry, 2024 - nature.com
Multi-site functionalization of molecules provides a potent approach to accessing intricate
compounds. However, simultaneous functionalization of the reactive site and the inert …

Recent developments in the difunctionalization of alkenes with C–N bond formation

X Chen, F Xiao, WM He - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
The difunctionalization of carbon–carbon double bonds, introducing two novel functional
groups onto both sides of the carbon–carbon bond in one pot, has become more and more …

Ni-catalyzed ligand-controlled regiodivergent reductive dicarbofunctionalization of alkenes

Q Pan, Y Ping, Y Wang, Y Guo… - Journal of the American …, 2021 - ACS Publications
Transition-metal-catalyzed dicarbofunctionalization of alkenes involving intramolecular Heck
cyclization followed by intermolecular cross-coupling has emerged as a powerful engine for …

Recent advances in first-row transition metal-catalyzed reductive coupling reactions for π-bond functionalization and C-glycosylation

Y Wei, LQH Lin, BC Lee, MJ Koh - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Efficient construction of ubiquitous carbon–carbon bonds between two
electrophiles has garnered interest in recent decades, particularly if it is mediated by …

Palladium (II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications

RI McDonald, G Liu, SS Stahl - Chemical reviews, 2011 - ACS Publications
The development of catalytic reactions of alkenes transformed the chemical industry in the
mid-20th century. Representative reactions included hydrogenation, oxidation …