Metallacrown (MC) research grows each year, in particular with regard to applications of
these molecules. This review will focus on the properties and applications of these …

Data on the synthesis and structure of water-soluble polynuclear copper (II) and lanthanide
(III) metallamacrocycles based on amino hydroxamic acids are presented. The structural …

Abstract The tetraaqua lanthanide 15-metallacrown-5 Ln (H 2 O) 4 [15MC CuGlyha-5](Cl) 3
complexes have been synthesized under ambient conditions from copper (II) acetate and …

The water‐soluble copper (II)‐lanthanum (III) complex based on phenylalaninehydroximate
ligands La (H2O) 4 [15‐MCCuPhalaha‐5](Cl) 3 (1) has been synthesized and characterized …

Angelica Sinensis polysaccharide cerium (ASP− Ce) was prepared by Angelica Sinensis
polysaccharide (ASP) and cerium ammonium nitrate (NH4) 2Ce (NO3) 6. and its …

With an idea to explore the unique structure of the lanthanide 15‐MC‐5 metallacrowns, the
water‐soluble Cu (II)‐Ce (III) aqua‐complexes, bearing aminohydroximate (glycine‐and α …

Recently, aminohydroximate ligands have found wide applications in the fascinating class of
polynuclear metallamacrocyclic compounds named 15-MC-5 metallacrowns. The enhanced …

Among numerous metallacrowns, the 15-Metallacrown-5 (15-MC-5) systems represent an
exceptional class of heterometallic 3d–4f coordination compounds with unique structures …

It was shown by electronic spectroscopy that the visible absorption spectrum of the
polynuclear Cu (II)–Gd (III) metallamacrocyclic complex is pH-sensitive. The intensity of the …

A new family of LnIII [12-Metallacrown-4] compounds of formulas (C5H6N)[LnFe4 (shi) 4
(C6H5COO) 4 (Py) 4]· 3.5 Py [Ln= EuIII (1); GdIII (2); TbIII (3); DyIII (4); and, H3shi …