Synthesis and characterization of heterobimetallic iridium–aluminum and rhodium–aluminum complexes

TP Brewster, TH Nguyen, Z Li, WT Eckenhoff… - Inorganic …, 2018 - ACS Publications
We demonstrate the synthesis and characterization of a new class of late-transition-metal–
aluminum heterobimetallic complexes via a novel synthetic pathway. Complexes of this type …

Hydrogen activation and hydrogenolysis facilitated by late-transition-metal–aluminum heterobimetallic complexes

RM Charles III, TW Yokley, ND Schley… - Inorganic …, 2019 - ACS Publications
Previously reported heterobimetallic rhodium–aluminum and iridium–aluminum alkyl
complexes are shown to activate hydrogen, generating the corresponding alkane. Kinetic …

Synthesis, coordination modes, structures, and magnetic properties of halogen-substituted 2-hydroxypyridine copper (II) chloride coordination compounds

MR Graci, FF Awwadi, DA Dickie… - Journal of …, 2024 - Taylor & Francis
Abstract A family of 6-X-2-hydroxyprydine/pyridone (6-X-2-HOpy/pyridone) Cu (II)
compounds,[Cu (6-X-2-HOpy) 2Cl2](1 X= F; 2 X= Cl) and [(6-X-2-pyridone) CuCl (μ-Cl)] 2 (3 …

Building coordination polymers using dipyridone ligands

M Mohan, T Maris, A Duong - CrystEngComm, 2020 - pubs.rsc.org
By examining the crystal structures of the self-assemblies of 1H, 1′ H-[3, 3′] bipyridinyl-6,
6′-dione 1 and its coordination structure with Co (II), to form novel CP-671, our study …

Pyridin-2-one in complexes, cocrystals and an ionic liquid. Syntheses, structures and thermal stability

S Petriček - Journal of Molecular Structure, 2022 - Elsevier
Reactions of anhydrous chlorides VCl 3 or ZnCl 2 and pyridin-2-one (C 5 H 5 NO= Hhp)
afforded novel homoleptic ionic [V (Hhp) 6] Cl 3. CH 2 Cl 2 (1) or molecular [ZnCl 2 (Hhp) …

Unusual coordination behavior by a hydroxypyridine/pyridone ligand: Synthesis and structure of [(2-bromo-4-hydroxypyridine)2(2-bromo-1(H)-4-pyridone)2copper(II) …

JC Monroe, MM Turnbull - Journal of Coordination Chemistry, 2019 - Taylor & Francis
The synthesis and structure of [Cu (2-Br-4-HOpy) 2 (2-Br-4-pyone) 2](ClO4) 2• 2 (2-Br-4-
HOpy)• 2 (2-Br-4-pyone) is reported [2-Br-4-HOpy= 2-bromo-4-hydroxypyridine; 2-Br-4 …

Structural diversity of nickel and manganese chloride complexes with pyridin-2-one

S Petriček - Molecules, 2020 - mdpi.com
Reactions of NiCl2· 6H2O and pyridin-2-one (C5H5NO= Hhp) afforded novel molecular
complexes, ie, mononuclear [NiCl2 (Hhp) 4](1), dinuclear [NiCl2 (Hhp)(H2O) 2] 2.2 Hhp (3) …

[PDF][PDF] Analysis of hydroformylation catalysis mechanisms of rhodium catalyst precursors by computational and instrumental means.

SJ O'Kennedy, WJ Gerber, SF Mapolie - 2021 - scholar.sun.ac.za
The most industrially prevalent hydroformylation catalysts are based mainly on cobalt or
rhodium with various combinations of carbonyl, halide or tertiary phosphine ligands and …