Locking effect in metal@ MOF with superior stability for highly chemoselective catalysis

Y Zhong, P Liao, J Kang, Q Liu, S Wang… - Journal of the …, 2023 - ACS Publications
Ultrasmall metal nanoparticles (NPs) show high catalytic activity in heterogeneous catalysis
but are prone to reunion and loss during the catalytic process, resulting in low …

In Situ Single-crystal X-ray Diffraction Studies of Physisorption and Chemisorption of SO2 within a Metal–Organic Framework and Its Competitive Adsorption with …

RM Main, SM Vornholt, R Ettlinger… - Journal of the …, 2024 - ACS Publications
Living on an increasingly polluted planet, the removal of toxic pollutants such as sulfur
dioxide (SO2) from the troposphere and power station flue gas is becoming more and more …

Optimum relative humidity enhances CO2 uptake in diamine-appended M2 (dobpdc)

HE Holmes, S Ghosh, C Li, J Kalyanaraman… - Chemical Engineering …, 2023 - Elsevier
Abstract Diamine-appended M 2 (dobpdc) metal–organic frameworks (MOFs) are a
promising class of CO 2 adsorbents, but the impact of relative humidity (RH) on their …

Green synthesis of polypyrrole for CO 2 capture from humid flue gases

Z Wang, Z Li, L Liu, P Cao, S Li, GK Li - Green Chemistry, 2023 - pubs.rsc.org
Post-combustion carbon capture from fossil fuels for concentrated sources such as power
plants is considered as one of the efficient ways to mitigate CO2 emissions. However …

Carbon capture phenomena in metal-organic frameworks with neural network potentials

Y Shaidu, A Smith, E Taw, JB Neaton - PRX Energy, 2023 - APS
Diamine-appended metal-organic frameworks are ultraporous materials exhibiting selective
and cooperative CO 2 adsorption mechanisms, leading to chemically tunable step-shaped …

Development of a chemistry-based isotherm model and techno-economic optimization of a moving bed process for CO2 capture using a functionalized metal-organic …

R Hughes, G Kotamreddy, D Bhattacharyya… - Chemical Engineering …, 2024 - Elsevier
Amine-appended metal–organic frameworks of the class Mg 2 (dobpdc) are promising
candidates for efficient carbon capture in part due to their step-shaped CO 2 adsorption …

Evaluating degradation of CO 2 adsorbents in flue gas from bioenergy with carbon capture and storage

HE Holmes, RD Schreck, P Narayanan… - Sustainable Energy & …, 2023 - pubs.rsc.org
The potential degradation of CO2 adsorbents in Bioenergy with Carbon Capture and
Storage (BECCS) was investigated through direct exposure to biomass combustion flue gas …

Precise Construction of Nitrogen‐Enriched Porous Ionic Polymers as Highly Efficient Sulfur Dioxide Adsorbent

S Chen, S Huang, Z Yang, X Suo, H Xing, X Cui - Small, 2024 - Wiley Online Library
Porous ionic polymers with unique features have exhibited high performance in various
applications. However, the fabrication of functional porous ionic polymers with custom …

Translocation and confinement of tetraamines in adaptable microporous cavities

A Rubio‐Gaspar, A Misturini, R Millan… - Angewandte …, 2024 - Wiley Online Library
Abstract Metal‐Organic Frameworks can be grafted with amines by coordination to metal
vacancies to create amine‐appended solid adsorbents, which are being considered as an …

Effect of the presence of trace sulfur dioxide on piperazine-based amine absorbents for carbon dioxide capture

S Zheng, Y Jiang, S Jia, Y Wu, P Cui - Chinese Journal of Chemical …, 2024 - Elsevier
The effect of the presence of trace SO 2 in industrial flue gas on the amine-scrubbing-based
absorption process for CO 2 capture has been a matter of concern. This study aimed to …