Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination

TR Cook, PJ Stang - Chemical reviews, 2015 - ACS Publications
The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

Self-assembled metal–organic polyhedra: An overview of various applications

H Vardhan, M Yusubov, F Verpoort - Coordination Chemistry Reviews, 2016 - Elsevier
Self-assembly is a potent synthetic tool that allowed chemists to design numerous complex
structures, supramolecules of various shapes from relatively simple starting materials. Metal …

Self-Assembled Pd12 Coordination Cage as Photoregulated Oxidase-Like Nanozyme

S Bhattacharyya, SR Ali… - Journal of the …, 2020 - ACS Publications
Designing supramolecular architectures with uncommon geometries embedded with
functional building units is of immense importance in contemporary research. In this report …

An adaptable water-soluble molecular boat for selective separation of phenanthrene from isomeric anthracene

AB Sainaba, M Venkateswarulu… - Journal of the …, 2022 - ACS Publications
Anthracene crude oil is a common source of phenanthrene for its industrial use. The
isolation of phenanthrene from this source is a challenging task due to very similar physical …

Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes

CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Mesopolymer synthesis by ligand-modulated direct arylation polycondensation towards n-type and ambipolar conjugated systems

Z Ni, H Wang, H Dong, Y Dang, Q Zhao, X Zhang… - Nature …, 2019 - nature.com
Conjugated polymers are attractive components for plastic electronics, but their structural
defects, low solubility and batch-to-batch variation—mainly in terms of molecular weight and …

General room-temperature Suzuki–Miyaura polymerization for organic electronics

H Xiong, Q Lin, Y Lu, D Zheng, Y Li, S Wang, W Xie… - Nature materials, 2024 - nature.com
Abstract π-Conjugated polymers (CPs) have broad applications in high-performance
optoelectronics, energy storage, sensors and biomedicine. However, developing green and …

Solvent Induced Conversion of a Self‐Assembled Gyrobifastigium to a Barrel and Encapsulation of Zinc‐Phthalocyanine within the Barrel for Enhanced Photodynamic …

V Abdul Rinshad, J Sahoo… - Angewandte …, 2023 - Wiley Online Library
A rare gyrobifastigium architecture (GB) was constructed by self‐assembly of a tetradentate
donor (L) with PdII acceptor in DMSO. The GB was converted to its isomeric tetragonal barrel …

From ring-in-ring to sphere-in-sphere: self-assembly of discrete 2D and 3D architectures with increasing stability

B Sun, M Wang, Z Lou, M Huang, C Xu… - Journal of the …, 2015 - ACS Publications
Directed by increasing the density of coordination sites (DOCS) to increase the stability of
assemblies, discrete 2D ring-in-rings and 3D sphere-in-sphere were designed and self …

Deconvoluting the role of charge in a supramolecular catalyst

CM Hong, M Morimoto, EA Kapustin… - Journal of the …, 2018 - ACS Publications
We have demonstrated that the microenvironment of a highly anionic supramolecular
catalyst can mimic the active sites of enzymes and impart rate accelerations of a million-fold …