2‐Propargyl Alcohols in Organic Synthesis

H Qian, D Huang, Y Bi, G Yan - Advanced Synthesis & Catalysis, 2019 - Wiley Online Library
Propargyl alcohols are widely used in organic reactions. Their great success is rooted in the
presence of multiple functional groups. This review will focus on six types of mechanisms:(i) …

Tandem annulations of propargylic alcohols to indole derivatives

XY Liu, YL Liu, L Chen - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Indole derivatives are important heterocycles in organic synthesis for serving as privileged
building blocks for functional material and as key components in a lot of bioactive …

2‐(Alkynyl) anilines and Derivatives—Versatile Reagents for Heterocyclic Synthesis

AA Festa, PV Raspertov… - Advanced Synthesis & …, 2022 - Wiley Online Library
The transformations of 2‐alkynylanilines and their derivatives into heterocycles are
surveyed. Depending on the substituents, catalysts, and reaction conditions, these …

[HTML][HTML] Synthesis of indoles via intermolecular and intramolecular cyclization by using Palladium-based catalysts

M Bilal, N Rasool, SG Khan, U Rashid, H Altaf, I Ali - Catalysts, 2021 - mdpi.com
As part of natural products or biologically active compounds, the synthesis of nitrogen-
containing heterocycles is becoming incredibly valuable. Palladium is a transition metal that …

An Unprecedented Pd‐Catalyzed Carbonylative Route to Fused Furo[3,4‐b]indol‐1‐ones

A Acerbi, C Carfagna, M Costa… - … A European Journal, 2018 - Wiley Online Library
A novel and efficient catalytic approach to functionalized furo [3, 4‐b] indol‐1‐ones is
reported. It is based on a palladium‐catalyzed sequential process involving an initial …

Dehydrogenative Cycloisomerization/Arylation Sequence of N‐Propargyl Carboxamides with Arenes by Iodine(III)‐Catalysis

Y Umakoshi, Y Takemoto, A Tsubouchi… - Advanced Synthesis …, 2022 - Wiley Online Library
Dehydrogenative cycloisomerization/arylation sequence of heteroatom nucleophile‐
tethered unactivated alkynes provides a facile and powerful approach to C− C bond …

Reactivity of Indolylmethylacetates with N, O, and S Soft Nucleophiles: Evidence of 2‐Alkylideneindolenines and 3‐Alkylideneindoleninium Generation by ESI‐MS …

A Arcadi, G Berden, A Ciogli, D Corinti… - European Journal of …, 2022 - Wiley Online Library
Abstract The synthesis of (aminomethyl),(tosylmethyl), and (aryloxymethyl) indoles starting
from indolylmethylacetates and N, O, and S soft nucleophiles has been developed. ESI‐MS …

Synthesis of 9, 10‐Dibenzoyl‐phenanthrene Derivatives Through a Palladium‐Catalyzed Domino Approach

A Arcadi, G Fabrizi, A Goggiamani… - Advanced Synthesis …, 2023 - Wiley Online Library
A palladium‐catalyzed domino approach toward synthetically challenging phenanthrene
derivatives has been developed. The procedure involves a sequence of oxidative …

Palladium-catalyzed Tsuji–Trost-type reaction of benzofuran-2-ylmethyl acetates with nucleophiles

A Arcadi, G Fabrizi, A Fochetti, F Ghirga… - RSC …, 2021 - pubs.rsc.org
The palladium-catalyzed benzylic-like nucleophilic substitution of benzofuran-2-ylmethyl
acetate with N, S, O and C soft nucleophiles has been investigated. The success of the …

BF3-promoted reactions between aryl aldehydes and 3-diazoindolin-2-imines: Access to 2-amino-3-arylindoles

K Huang, P Lu, Y Wang - Tetrahedron, 2019 - Elsevier
An efficient and highly regioselective synthesis of 2-amino-3-arylindoles via the BF 3-
promoted reaction of 3-diazoindolin-2-imines with aryl aldehydes is described. This reaction …