Anticancer and antibiotic rhenium tri-and dicarbonyl complexes: current research and future perspectives

K Schindler, F Zobi - Molecules, 2022 - mdpi.com
Organometallic compounds are increasingly recognized as promising anticancer and
antibiotic drug candidates. Among the transition metal ions investigated for these purposes …

Structural and Photophysical Trends in Rhenium (I) Carbonyl Complexes with 2, 2′: 6′, 2 ″-Terpyridines

J Palion-Gazda, K Choroba, AM Maroń, E Malicka… - Molecules, 2024 - mdpi.com
This is the first comprehensive review of rhenium (I) carbonyl complexes with 2, 2′: 6′, 2
″-terpyridine-based ligands (R-terpy)—encompassing their synthesis, molecular features …

Synthesis and study of Re (I) tricarbonyl complexes based on octachloro-1, 10-phenanthroline: Towards deep red-to-NIR emitters

AV Artem'ev, MY Petyuk, AS Berezin, AL Gushchin… - Polyhedron, 2021 - Elsevier
To shift the emission of classical [Re (CO) 3 (N^ N) X] 0/+ complexes to the NIR region, we
have proposed a novel and efficient design strategy based on perchlorination of the diimine …

Computational design of rhenium (I) carbonyl complexes for anticancer photodynamic therapy

D Álvarez, MI Menéndez, R López - Inorganic chemistry, 2021 - ACS Publications
New Re (I) carbonyl complexes are proposed as candidates for photodynamic therapy after
investigating the effects of the pyridocarbazole-type ligand conjugation, addition of …

Effect of the Appended Morpholinyl Group on Photophysical Behavior of Mono-and Bis-cyclometalated Terpyridine Iridium (III) Chromophores

J Palion-Gazda, A Kwiecień, K Choroba… - Inorganic …, 2024 - ACS Publications
This paper provides extensive studies of [IrCl (Ph-py)(morph-C6H4-terpy-κ3N)] PF6 (1A),[Ir
(Ph-py) 2 (morph-C6H4-terpy-κ2N)] PF6 (2A),[IrCl (Ph-py)(Ph-terpy-κ3N)] PF6 (1B), and [Ir …

Further Insights into the Impact of Ligand-Localized Excited States on the Photophysics of Phenanthroline-Based Rhenium (I) Tricarbonyl Complexes

J Palion-Gazda, K Choroba, M Penkala… - Inorganic …, 2023 - ACS Publications
The present work shows the pivotal role of N-donor substituents attached to 1, 10-
phenanthroline at the 4, 7-positions in perturbation of ground-and excited-state properties of …

Dissecting conjugation and electronic effects on the linear and non-linear optical properties of rhenium (i) carbonyl complexes

RJ Fernández-Terán, E Sucre-Rosales… - Physical Chemistry …, 2022 - pubs.rsc.org
Herein, we report a theoretical and experimental analysis of the conjugation and electronic
effects on the one-photon (1PA) and two-photon absorption (2PA) properties of a series of …

Electrocatalytic reduction of CO 2 to CO by a series of organometallic Re (i)-tpy complexes

S Saha, T Doughty, D Banerjee, SK Patel… - Dalton …, 2023 - pubs.rsc.org
A series of organometallic Re (I)(L)(CO) 3Br complexes with 4′-substituted terpyridine
ligands (L) has been synthesised as electrocatalysts for CO2 reduction. The complexes' …

Photostimulated Anticancer Activity of Mitochondria Localized Rhenium(I) Tricarbonyl Complexes Bearing 1H‐imidazo[4,5‐f][1,10]phenanthroline Ligands Against …

B Kar, P Paira - Chemistry–A European Journal, 2024 - Wiley Online Library
We have introduced Re (I) tricarbonyl complexes (ReL1‐ReL6)[Re (CO) 3 (N^ N) Cl] where
N^ N= extensive π conjugated imidazo‐[4, 5‐f][1, 10]‐phenanthroline derivatives that helps …

Electronic Properties of Rhenium (I) Carbonyl Complexes Bearing Strongly Donating Hexahydro‐Pyrimidopyrimidine Based Ligands

T Auvray, AK Pal, GS Hanan - European Journal of Inorganic …, 2021 - Wiley Online Library
Re (I) tricarbonyl complexes have been synthesized using bi‐and tridentate ligands
equipped with one or two hexahydro‐pyrimidopyrimidine (hpp) units attached to either a …