There exists a paucity of structural innovation and limited molecular diversity associated with
molecular frameworks in drug discovery and biomolecular imaging/chemical probe design …

Conspectus Carboranes are a class of polyhedral carbon–boron molecular clusters
featuring three-dimensional aromaticity, which are often considered as 3D analogues of …

Boron cluster compounds are inorganic compounds with chemical compositions and
structures vastly different from those of organic compounds, albeit with the ability to form a …

Amination of carboranes has a good application prospect in organic and pharmaceutical
synthesis. However, the current methods used for this transformation suffer from limitations …

Aromatic polycyclic systems have been extensively utilized as structural subunits for the
preparation of various functional molecules. Currently, aromatics-based polycyclic systems …

The efficient and selective functionalization of icosahedral carboranes (C2B10H12) at the
boron vertexes is a long-standing challenge owing to the presence of 10 inert B–H bonds in …

Cyclodextrin (CD)-based supramolecular hydrogels are polymer network systems with the
ability to rapidly form reversible three-dimensional porous structures through multiple cross …

Herein, we present a chemically robust and efficient synthesis route for B (9)-OH-o-
carboranes by the oxidation of o-carboranes with commercially available 68% HNO3 under …

Herein, we report the unique solid‐state excimer emission of three types of acridine‐
tethered o‐carboranes with variable degrees of methylation at the o‐carborane unit. They all …

Carborynes (1, 2-dehydro-o-carborane and 1, 3-dehydro-o-carborane), three-dimensional
analogues of benzyne, can be generated in situ from the precursors 1-X-2-Li-1, 2 …