Herein, we report carbene-mediated benzannulation of vinyl sulfoxonium ylides with
electron-deficient alkynes and alkenes to synthesize oxygenated arenes. This protocol …

The present review is a comprehensive update of the synthesis of monocyclic β-lactams via
cycloaddition reactions. According to the IUPAC definition of cycloaddition, both elementary …

The direct trifluoromethylthiolation of aziridines with AgSCF3 and iodides is reported. The β-
trifluoromethylthiolated isothiocyanates and amines were selectively obtained by the …

We report a stereoselective synthesis of conjugated di-and trienamides from the direct one
pot γ-selective union of a dienolate and chiral nonconjugated and conjugated sulfinyl …

A unique direct asymmetric synthesis of α‐aminoimines is realized, through rapid and
exclusive mono‐allylation of chiral bis‐N‐sulfinylimines using allylboronic acids. The highly …

We report a detailed study on the synthesis and aldehyde vinylogation applications of chiral
N-sulfinyl imine phosphonate reagents. Two complementary scalable reagent routes, from …

We report a new anionic cascade for assembling 2, 4-substituted benzoate esters in one pot
from racemic β-fluoro-substituted conjugated tert-butylsulfinyl imines and 3-substituted …

The efficient assembly of complex aromatic structures from simple acyclic building blocks is
reported. An anion-cascade union of an enoate and a conjugated imine affords …

Anionic Diels–Alder chemistry of electron-deficient cross-conjugated vinylogous alkenones,
providing highly stable sodium dienolate ion pairs as electron-rich dienes in the presence of …

Kinetic and thermodynamic challenges associated with the Cope rearrangements of 3, 3-
dicyano-1, 5-dienes have been studied and circumvented through reaction development …