Slow magnetic relaxation in a europium (II) complex
D Errulat, KLM Harriman, DA Gálico… - Nature …, 2024 - nature.com
Single-ion anisotropy is vital for the observation of Single-Molecule Magnet (SMM)
properties (ie, a slow dynamics of the magnetization) in lanthanide-based systems. In the …
properties (ie, a slow dynamics of the magnetization) in lanthanide-based systems. In the …
Isolation and electronic structures of lanthanide (II) bis (trimethylsilyl) phosphide complexes
J Baldwin, A Brookfield, GFS Whitehead… - Inorganic …, 2024 - ACS Publications
While lanthanide (Ln) silylamide chemistry is mature, the corresponding silylphosphide
chemistry is underdeveloped, with [Sm {P (SiMe3) 2}{μ-P (SiMe3) 2} 3Sm (THF) 3] being the …
chemistry is underdeveloped, with [Sm {P (SiMe3) 2}{μ-P (SiMe3) 2} 3Sm (THF) 3] being the …
Tetravalent Terbium Chelates: Stability Enhancement and Property Tuning
Coordination chemistry of rare-earth elements has been dominated by the+ 3 oxidation
state. Complexes with higher-valence lanthanide ions are synthetically challenging but are …
state. Complexes with higher-valence lanthanide ions are synthetically challenging but are …
Magnetic anisotropy in octahedral Dy (iii) and Yb (iii) complexes
New organophosphate complexes [Ln (dippH) 3 (dippH2) 3]·(H2O) 6,(Ln= Dy, Yb and Y;
dippH2= 2, 6-diisopropylphenyl phosphate), displaying octahedral coordination geometry …
dippH2= 2, 6-diisopropylphenyl phosphate), displaying octahedral coordination geometry …