The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Covalent organic frameworks (COFs) are structurally tuneable, porous and crystalline
polymers constructed through the covalent attachment of small organic building blocks as …

Visible light‐mediated direct decarboxylation of carboxylic acids with an acridine
photocatalyst is a convenient and powerful method to generate carbon‐centered radicals in …

sulfinamides, sulfonamides, and sulfonimidamides are in-demand motifs in medicinal
chemistry, yet methods for the synthesis of alkyl variants that start from simple, readily …

The value of catalytic dehydrogenation of aliphatics (CDA) in organic synthesis has
remained largely underexplored. Known homogeneous CDA systems often require the use …

We establish a synthetically convenient method to degrade polyacrylate homopolymers.
Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester …