Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

A long-standing challenge in synthetic chemistry is the direct, selective functionalization of
alkyl, alkenyl, and aryl CH bonds. Much research has been devoted to the selective …

This paper is part of a short series that celebrates the addition of the 500 000th crystal
structure to the Cambridge Structural Database in November 2009. The number of structures …

A series of studies have been conducted by experimental and theoretical methods on the
synthesis, structures, and reactions of Cp* Rh boryl complexes that are likely intermediates …

Since the publication of the last review in 1998, the transition‐metal chemistry of boron has
continued to raise unceasing interest. Boryl complexes, representing the most extensive …

We synthesized a PBP pincer ligand precursor 2 and demonstrated its complexation with
iridium (I) to afford the coordinatively unsaturated [PBP](hydrido) chloroiridium complex 3 via …

Transition‐metal‐mediated metalation of an aromatic C− H bond that is adjacent to a tertiary
phosphine group in arylphosphines via a four‐membered chelate ring was first discovered …

In this feature article, we discuss selected recent aspects of metal boryl (M–BR2) chemistry
pertaining, in particular, to the role of late and post-transition metal boryl complexes in …

Compounds with carbon–boron bonds are versatile intermediates for building more complex
molecules via the elaboration of the carbon–boron bonds into other carbon–element bonds …

The detailed mechanism for the diboration of aldehydes catalyzed by (NHC) Cu (boryl)
complexes (NHC= N-heterocyclic carbene) was studied with the aid of DFT by calculating …