A series of achiral and chiral diene and the related ligands in transition-metal complexes is
evaluated by percent buried volume (% V bur) based on their molecular structures by X-ray …

Conspectus Low-coordinate transition-metal species, ie, metal species with coordination
numbers of less than 4, represent a category of ubiquitous reactive intermediates in metal …

Late-transition-metal-based catalysts are widely used in N2 fixation reactions, but the
reactivity of late-transition-metal N2 complexes, besides iron N2 complexes, has remained …

Planar, low-spin cobalt (II) dialkyl complexes bearing bidentate phosphine ligands,(P–P) Co
(CH2SiMe3) 2, are active for the hydrogenation of geminal and 1, 2-disubstituted alkenes …

Abstract An anionic Rh− Ga complex catalyzed the hydrodefluorination of challenging C− F
bonds in electron‐rich aryl fluorides and trifluoromethylarenes when irradiated with violet …

Chloride abstraction from the group 9 metal bis (N-heterocyclic carbene) complexes M
(NHC) 2 (H) 2Cl [M= Rh, Ir; NHC= IPr= N, N′-bis (2, 6-diisopropylphenyl) imidazol-2 …

Iridium (i) complexes containing a (5H‐dibenzo [a, d] cyclohepten‐5‐yl)‐phosphane
(troppR; R= phosphorus‐bound substituent= Ph, Cyc) as a rigid, concave‐shaped, mixed …

A simple synthesis of a chiral phosphane alkene (PAL) involves: 1) palladium‐catalyzed
Suzuki coupling of 10‐bromo‐5H‐dibenzo [a, d] cyclohepten‐5‐ol (1) with phenylboronic …

The reaction of [Ir (coe) 2Cl] 2 (coe= cyclooctene) with the N-heterocyclic carbene N, N′-bis
(2, 6-diisopropylphenyl) imidazol-2-ylidene (IPr) in tetrahydrofuran under anaerobic …

We have investigated the influence of bound cations on the reduction of cobalt complexes of
redox active ligands and explored the reactivity of reduced species with CO2. The one …