Zinc Aryl/Alkyl β-diketiminates: Balancing Accessibility and Stability for High-Activity Ring-Opening Polymerization of rac-Lactide

JE Chellali, AK Alverson, JR Robinson - ACS Catalysis, 2022 - ACS Publications
The development of nontoxic initiators which display both high activity and stability at low
catalyst concentrations can be challenging, as these desired attributes often involve …

Crystallization behavior analysis and reducing thermal shrinkage of poly (lactic acid) miscibilized with poly (butylene succinate) film for food packaging

P Jariyasakoolroj, K Makyarm… - Journal of Applied …, 2023 - Wiley Online Library
Abstract Poly (lactic acid)(PLA) incorporated with poly (butylene succinate)(PBS) through in
situ reactive blending is proposed to retard thermal shrinkage. Succinic anhydride (SA) with …

Easy access to ultra-high molecular weight polylactones using a bismuth catalyst

F Li, S Rastogi, D Romano - Journal of Catalysis, 2022 - Elsevier
A facile method for the preparation of ultra-high molecular weight of polylactides and poly (ε-
caprolactone) with relatively narrow polydispersity index using BiPh 2 Br catalyst is …

Thermo-rheological and shape memory properties of block and random copolymers of lactide and ε-caprolactone

M Naddeo, A Sorrentino, D Pappalardo - Polymers, 2021 - mdpi.com
Biodegradable block and random copolymers have attracted numerous research interests in
different areas, due to their capability to provide a broad range of properties. In this paper …

Phenoxy-imine/-amide aluminum complexes with pendant or coordinated pyridine moieties: Solvent effects on structural type and catalytic capability for the ROP of …

Y Jiang, W Zhang, M Han, X Wang, GA Solan, R Wang… - Polymer, 2022 - Elsevier
Depending on the solvent employed, the dimeric aluminum phenoxyamide complexes [2-O,
4-R 4 C 6 H 3 CHMeN (3′-R 1, 4′-R 2, 5′-R 3 C 5 HN)] 2 Al 2 Me 2 (R 1= Me, R 2= R 3 …

Single Crystals of Ultrahigh Molecular Weight Poly(ethylene-alt-CO)s for Solvent-Free Processing and Enhanced Thermal Stability

M Thaliyil Puthiyaveettil, SK Raman, J Zhao… - …, 2024 - ACS Publications
Aliphatic polyketone poly (ethylene-alt-CO)(PK-E) is a remarkable material known for its
exceptional thermal and mechanical properties, potential photodegradability, and overall …

On the Influence of the cis/trans Stereochemistry of Limonene Oxides toward the Synthesis of Biobased Thermosets by Crosslinking with Anhydrides

E Louisy, S Olivero, V Michelet… - … Sustainable Chemistry & …, 2022 - ACS Publications
This study emphasizes the reactivity of (R)-(+)-limonene, a major byproduct of the citrus
industry, and its potential to be used as a biobased thermoset precursor. We separated the …

Synthesis and Characterization of High-Molecular-Weight PLAs with a Well-Controlled Particle Morphology

F Li, S Rastogi, D Romano - Industrial & Engineering Chemistry …, 2023 - ACS Publications
The synthesis of high-/ultrahigh-molecular-weight poly (l-lactide)(PLLA) having a controlled
morphology remains a challenge because of the low crystallization rate of the material and …

[HTML][HTML] Comparison of accelerated and enzyme-associated real-time degradation of HMW PLLA and HMW P3HB films

D Arbeiter, K Lebahn, T Reske, V Senz, T Eickner… - Polymer Testing, 2022 - Elsevier
Designing laboratory-scale degradation experiments for polymer-based biomaterials is
crucial for the development of safe and functional implants, in particular regarding high …

Synthesis and Structural Characterisation of Dinuclear Aluminium Complexes Supported by NNO‐Tridentate Schiff‐Base Ligands and Their Catalysis in the Ring …

X Yu, Z Wang, Z Han - ChemistrySelect, 2021 - Wiley Online Library
In this study, we prepared a series of dinuclear aluminium complexes {Bis {2‐OAlMe2‐3‐
CH= N [CH2CH2N (CH3) 2]‐5‐CH3C6H2} CH2, Bis [2‐OAlMe2‐3‐CH= N (2‐PyCH2)‐5 …